Interfacial Strengthening and Stress Mitigation in GH4169/Ti60 Diffusion-Bonded Joints Driven by Cu Interlayer Thickness Design

Abstract Heterogeneous joining of GH4169 Ni-based superalloy and Ti60 titanium alloy combines their advantages, but brittle Ti-Ni phases and stress concentration lower joint strength. Here, pure Cu interlayers were used for diffusion bonding GH4169/Ti60 joints. The Cu foil thickness was varied to study microstructural evolution and reveal strengthening and fracture mechanisms. Direct TLP bonding produces a joint comprising diffusion layer I (GH4169 side), central brazing seam II, and diffusion layer III (Ti60 side), with typical microstructure GH4169/Cr ss +(Ni,Cr,Fe) ss /TiNi/Ti 2 Ni/α-Ti/Ti60; brittle TiNi compounds degrade performance. With Cu foil, the typical microstructure becomes Ti(Ni,Cu)/TiCu+TiAl/β-Ti+Ti 3 Sn/α-Ti+Ti 2 Cu/α-Ti/Ti60. Increasing Cu thickness coarsens zone II grains and reduces the high-angle grain boundary fraction from 92.5% to 46.1%. At 0.03mm Cu, the maximum KAM values in zones I, II, and III are 4.88°, 4.99°, and 4.97°, respectively, indicating relatively uniform stress. The (Ni,Cu) ss /Ti 3 Sn/Ti–Cu layered structure in zone II greatly relieves residual stress and gives a maximum joint strength of 190MPa. Fracture morphology and path indicate brittle fracture; cracks initiate between the (Cu,Ni) ss and TiCu phases and form small secondary cracks.

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Publication Details

Journal
Research Square
Published
2026-11-11
DOI
https://doi.org/10.21203/rs.3.rs-11249178/v1
Primary Topic
Advanced Welding Techniques Analysis
Type
preprint
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preprint

Interfacial Strengthening and Stress Mitigation in GH4169/Ti60 Diffusion-Bonded Joints Driven by Cu Interlayer Thickness Design

Ranfeng Qiu, Zhiqian Liao, Kaiyang Zhang, Hua YU et al.
Research Square
Advanced Welding Techniques Analysis
preprint

Interfacial Strengthening and Stress Mitigation in GH4169/Ti60 Diffusion-Bonded Joints Driven by Cu Interlayer Thickness Design

Ranfeng Qiu, Zhiqian Liao, Kaiyang Zhang, Hua YU, Shibo Zhu, Sen Yang, Zhuoli Yu, Liangliang Zhang, Tao Jiang, Yanan Zhang, Qi Gao, Li Ma, Xingxing Wang
preprint en

Abstract

Abstract Heterogeneous joining of GH4169 Ni-based superalloy and Ti60 titanium alloy combines their advantages, but brittle Ti-Ni phases and stress concentration lower joint strength. Here, pure Cu interlayers were used for diffusion bonding GH4169/Ti60 joints. The Cu foil thickness was varied to study microstructural evolution and reveal strengthening and fracture mechanisms. Direct TLP bonding produces a joint comprising diffusion layer I (GH4169 side), central brazing seam II, and diffusion layer III (Ti60 side), with typical microstructure GH4169/Cr ss +(Ni,Cr,Fe) ss /TiNi/Ti 2 Ni/α-Ti/Ti60; brittle TiNi compounds degrade performance. With Cu foil, the typical microstructure becomes Ti(Ni,Cu)/TiCu+TiAl/β-Ti+Ti 3 Sn/α-Ti+Ti 2 Cu/α-Ti/Ti60. Increasing Cu thickness coarsens zone II grains and reduces the high-angle grain boundary fraction from 92.5% to 46.1%. At 0.03mm Cu, the maximum KAM values in zones I, II, and III are 4.88°, 4.99°, and 4.97°, respectively, indicating relatively uniform stress. The (Ni,Cu) ss /Ti 3 Sn/Ti–Cu layered structure in zone II greatly relieves residual stress and gives a maximum joint strength of 190MPa. Fracture morphology and path indicate brittle fracture; cracks initiate between the (Cu,Ni) ss and TiCu phases and form small secondary cracks.

Research Square
Henan University of Science and Technology (CN), North China University of Water Resources and Electric Power (CN), Henan Polytechnic University (CN), Luoyang Ship Material Research Institute (CN)
Advanced Welding Techniques Analysis
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