Composite Multigraphene Gaskets with Ultra-Reduced Fugitive Emissions

An automatic technological line to produce a three-layer composite material based on a steel base and multigraphene tapes as fillers in spiral-wound gaskets was developed. It has been experimentally shown that multigraphene materials have a pronounced anisotropy of gas permeability due to a layered-porous microstructure. The longitudinal gas permeability of multigraphene materials obtained from intercalated graphite compounds is 20.3·10−3 mg/(m·s) for stage II and 22.9·10−3 mg/(m·s) for stage IV, while the transverse permeability is significantly lower and amounts to 0.75·10−3 mg/(m·s) for stage II and 0.85·10−3 mg/(m·s) for stage IV, respectively. The in-plane gas permeability of the composite based on stage II multigraphene is reduced to 5.8·10−3 mg/(m·s) due to the barrier effect of the metal tape. The recoverability of the composite increases to 19% with compressibility of 34%. To achieve the tightness class L0.0000001, it is proposed to manufacture spiral-wound gaskets from a three-layer composite based on stage II multigraphene with a fluoropolymer sealing coating. This made it possible to significantly reduce fugitive emissions through the composite gaskets.

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Publication Details

Journal
Journal of Manufacturing and Materials Processing
Published
2026-11-11
DOI
https://doi.org/10.3390/jmmp10110501
Primary Topic
Polymer Nanocomposites and Properties
Type
article
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article

Composite Multigraphene Gaskets with Ultra-Reduced Fugitive Emissions

Vladimir A. Shulyak, Kristina E. Klyukova, Victor Vasil’evich Avdeev, Sergei N. Chebotarev et al.
Journal of Manufacturing and Materials Processing
Polymer Nanocomposites and Properties
article

Composite Multigraphene Gaskets with Ultra-Reduced Fugitive Emissions

Vladimir A. Shulyak, Kristina E. Klyukova, Victor Vasil’evich Avdeev, Sergei N. Chebotarev, Alexandra V. Gracheva, Nikolai S. Morozov, V. Yu. Gubin, Ildar Nigmatullin, David Demchenko
article en

Abstract

An automatic technological line to produce a three-layer composite material based on a steel base and multigraphene tapes as fillers in spiral-wound gaskets was developed. It has been experimentally shown that multigraphene materials have a pronounced anisotropy of gas permeability due to a layered-porous microstructure. The longitudinal gas permeability of multigraphene materials obtained from intercalated graphite compounds is 20.3·10−3 mg/(m·s) for stage II and 22.9·10−3 mg/(m·s) for stage IV, while the transverse permeability is significantly lower and amounts to 0.75·10−3 mg/(m·s) for stage II and 0.85·10−3 mg/(m·s) for stage IV, respectively. The in-plane gas permeability of the composite based on stage II multigraphene is reduced to 5.8·10−3 mg/(m·s) due to the barrier effect of the metal tape. The recoverability of the composite increases to 19% with compressibility of 34%. To achieve the tightness class L0.0000001, it is proposed to manufacture spiral-wound gaskets from a three-layer composite based on stage II multigraphene with a fluoropolymer sealing coating. This made it possible to significantly reduce fugitive emissions through the composite gaskets.

Journal of Manufacturing and Materials ProcessingVol. 10(11)
Lomonosov Moscow State University (RU)
Polymer Nanocomposites and Properties
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