Broadband Quantum Optical Storage with Chemically Engineered Molecular Eu$^\text{3+}$ Complex — E8 Intelligence Research

Broadband quantum memory devices are essential elements for future quantum networks. Here we propose a broadband quantum memory scheme called Hole Anti-hole Grating Echo Memory (HAGEM) for rare-earth ions in solids. We provide a Eu$^\text{3+}$ molecular complex with special hyperfine level structures of which the hyperfine level separations are in a specific mathematical correlation that can be obtained by harnessing chemical engineering. Using the memory protocol and material, we experimentally demonstrate a quantum optical storage efficiency of 14.9% and a memory bandwidth of 200MHz, which can easily be extended to a few GHz. With this demonstration, we show the first quantum application enabled by molecular engineering which cannot be achieved by any other existing Eu$^\text{3+}$ solid-state materials. In addition, we provide a framework for the chemical engineering of solid-state materials with rare-earth ions for quantum applications consisting of material design, synthesis & char Author: Andrew Stewart Caldin, Independent Researcher, UK. Part of the E8 Intelligence Research series. Platform: e8intelligence.com

Authors

Publication Details

Journal
Zenodo (CERN European Organization for Nuclear Research)
Published
2026-11-11
DOI
https://doi.org/10.5281/zenodo.24127554
Primary Topic
Quantum optics and atomic interactions
Type
preprint
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preprint

Broadband Quantum Optical Storage with Chemically Engineered Molecular Eu$^\text{3+}$ Complex — E8 Intelligence Research

Andrew Stewart Caldin
Zenodo (CERN European Organization for Nuclear Research)
Quantum optics and atomic interactions
preprint

Broadband Quantum Optical Storage with Chemically Engineered Molecular Eu$^\text{3+}$ Complex — E8 Intelligence Research

Andrew Stewart Caldin
preprint en

Abstract

Broadband quantum memory devices are essential elements for future quantum networks. Here we propose a broadband quantum memory scheme called Hole Anti-hole Grating Echo Memory (HAGEM) for rare-earth ions in solids. We provide a Eu$^\text{3+}$ molecular complex with special hyperfine level structures of which the hyperfine level separations are in a specific mathematical correlation that can be obtained by harnessing chemical engineering. Using the memory protocol and material, we experimentally demonstrate a quantum optical storage efficiency of 14.9% and a memory bandwidth of 200MHz, which can easily be extended to a few GHz. With this demonstration, we show the first quantum application enabled by molecular engineering which cannot be achieved by any other existing Eu$^\text{3+}$ solid-state materials. In addition, we provide a framework for the chemical engineering of solid-state materials with rare-earth ions for quantum applications consisting of material design, synthesis & char Author: Andrew Stewart Caldin, Independent Researcher, UK. Part of the E8 Intelligence Research series. Platform: e8intelligence.com

Zenodo (CERN European Organization for Nuclear Research)
Quantum optics and atomic interactions
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