Copper-catalysed Cascade Nitration/Cyclisation of Biaryl Enones using CAN: Access to Functionalised Phenanthrones
An efficient approach for the synthesis of nitro functionalised phenanthrones bearing all carbon quaternary centres has been developed via tandem nitrative annulation of biaryl enones with CAN reagent as nitro radical source. The reaction sequence involves a sequential addition of nitro radical to the olefin followed by intramolecular cyclisation.
Authors
- Chada Raji Reddy (ORCID: https://orcid.org/0000-0003-1491-7381)
- Uprety Ajaykumar
- Raju Adepu (ORCID: https://orcid.org/0000-0002-4437-1597)
- Aratikumari Suresh Prasad
- Shrikant Suresh Mudgal
Institutions
- Indian Institute of Chemical Technology (IN)
- Academy of Scientific and Innovative Research (IN)
Publication Details
- Journal
- Synlett
- Published
- 2026-11-11
- DOI
- https://doi.org/10.1055/a-3002-2551
- Primary Topic
- Radical Photochemical Reactions
- Type
- article
- Field-Weighted Citation Impact
- 0.00