Electron-Driven Ag Migration and Interfacial Growth in ZIF-8/α-Ag2WO4 Heterostructures

Abstract ZIF-8/α-Ag2WO4 heterostructures were designed to investigate electron-driven Ag evolution at MOF–semiconductor interfaces. In situ electron microscopy revealed structural integration and preferential Ag nanoparticle growth on ZIF-8 under irradiation. Interfacial charge redistribution is proposed to mediate this process, offering opportunities for catalytic, sensing, and antimicrobial applications.

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Publication Details

Journal
Inorganic Chemistry
Published
2026-11-11
DOI
https://doi.org/10.1021/acs.inorgchem.6c05500
Primary Topic
Metal-Organic Frameworks: Synthesis and Applications
Type
article
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article

Electron-Driven Ag Migration and Interfacial Growth in ZIF-8/α-Ag2WO4 Heterostructures

Julio Ricardo Sambrano, E. Longo, Henrique Moreno, Marcelo Assis et al.
Inorganic Chemistry
Metal-Organic Frameworks: Synthesis and Applications
article

Electron-Driven Ag Migration and Interfacial Growth in ZIF-8/α-Ag2WO4 Heterostructures

Julio Ricardo Sambrano, E. Longo, Henrique Moreno, Marcelo Assis, Marcio Daldin Teodoro, Juán Andrés, Giovanna A. Grasser
article en

Abstract

Abstract ZIF-8/α-Ag2WO4 heterostructures were designed to investigate electron-driven Ag evolution at MOF–semiconductor interfaces. In situ electron microscopy revealed structural integration and preferential Ag nanoparticle growth on ZIF-8 under irradiation. Interfacial charge redistribution is proposed to mediate this process, offering opportunities for catalytic, sensing, and antimicrobial applications.

Inorganic Chemistry
Universitat Jaume I (ES), Universidade Federal de São Carlos (BR), Universidade Estadual Paulista (Unesp) (BR)
Metal-Organic Frameworks: Synthesis and Applications
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