A Homoleptic Biradicaloid‐Ligated Analogue of Ferrocene
ABSTRACT In this communication, we report the synthesis, characterisation and electronic structure of a ferrocene analogue containing two biradicaloid ligands, representing the first homoleptic sandwich complex in this ligand class. In this quest, we found that the target compound was unattainable via routes involving Fe(0) or Fe(II) intermediates, and counterintuitively that the rare and much less‐explored +1 oxidation state was crucial for the synthesis.
Authors
- Oliver P. E. Townrow (ORCID: https://orcid.org/0000-0001-9556-6450)
- Oksana Storcheva
- Robert Kruk (ORCID: https://orcid.org/0000-0003-4951-0717)
- Peter Coburger (ORCID: https://orcid.org/0000-0003-1387-4148)
- Michael Neuwirt (ORCID: https://orcid.org/0000-0002-1875-181X)
- David Zuber
Institutions
- Karlsruhe Institute of Technology (DE)
- Technical University of Munich (DE)
Publication Details
- Journal
- Angewandte Chemie
- Published
- 2026-11-08
- DOI
- https://doi.org/10.1002/ange.8019368
- Primary Topic
- Ferrocene Chemistry and Applications
- Type
- article
- Field-Weighted Citation Impact
- 0.00
Funders
- Verband der Chemischen Industrie
- Deutsche Forschungsgemeinschaft