Spontaneous Symmetry Breaking in Posner Molecules Enables Long-Lived Nuclear Spin Coherence — E8 Intelligence Research

FINDING: Posner molecule (Ca₉(PO₄)₆) dynamical ensemble exhibits spontaneous symmetry breaking — the time-averaged structure lacks the full symmetry of the static minimum-energy configuration, with phosphate ions undergoing hindered rotations that lift degeneracies in the ³¹P nuclear spin Hamiltonian, enabling long-lived quantum coherence via symmetry-protected subspaces. MATH: Ca₉(PO₄)₆ cluster; ³¹P nuclear spin-1/2 system (6 phosphates × 1 spin each = 6-qubit register); Hamiltonian H = Σ Jᵢⱼ Iᵢ·Iⱼ + Σ γB·Iᵢ + H_dipolar; coherence time T₂ extended by dynamical decoupling from rotational diffusion (τ_rot ~ 10⁻⁹–10⁻⁶ s); symmetry group reduction from S₆ (static) to C₁/C₂ (dynamical ensemble) CONNECTION: Phosphate tetrahedra (PO₄) embody crystallographic point group T_d (tetrahedral symmetry, order 24) — root system A₃; Ca₉ core approximates tricapped trigonal prism (D₃h symmetry); symmetry breaking pattern T_d → C₃/C₁ mirrors spontaneous symmetry breaking in gauge theories; no golden Author: Andrew Stewart Caldin, Independent Researcher, UK. Part of the E8 Intelligence Research series. Platform: e8intelligence.com

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Publication Details

Journal
Zenodo (CERN European Organization for Nuclear Research)
Published
2026-11-07
DOI
https://doi.org/10.5281/zenodo.24029250
Primary Topic
Advanced NMR Techniques and Applications
Type
preprint
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Spontaneous Symmetry Breaking in Posner Molecules Enables Long-Lived Nuclear Spin Coherence — E8 Intelligence Research

Andrew Stewart Caldin
10 links
Zenodo (CERN European Organization for Nuclear Research)
Advanced NMR Techniques and Applications
preprint

Spontaneous Symmetry Breaking in Posner Molecules Enables Long-Lived Nuclear Spin Coherence — E8 Intelligence Research

Andrew Stewart Caldin
preprint en

Abstract

FINDING: Posner molecule (Ca₉(PO₄)₆) dynamical ensemble exhibits spontaneous symmetry breaking — the time-averaged structure lacks the full symmetry of the static minimum-energy configuration, with phosphate ions undergoing hindered rotations that lift degeneracies in the ³¹P nuclear spin Hamiltonian, enabling long-lived quantum coherence via symmetry-protected subspaces. MATH: Ca₉(PO₄)₆ cluster; ³¹P nuclear spin-1/2 system (6 phosphates × 1 spin each = 6-qubit register); Hamiltonian H = Σ Jᵢⱼ Iᵢ·Iⱼ + Σ γB·Iᵢ + H_dipolar; coherence time T₂ extended by dynamical decoupling from rotational diffusion (τ_rot ~ 10⁻⁹–10⁻⁶ s); symmetry group reduction from S₆ (static) to C₁/C₂ (dynamical ensemble) CONNECTION: Phosphate tetrahedra (PO₄) embody crystallographic point group T_d (tetrahedral symmetry, order 24) — root system A₃; Ca₉ core approximates tricapped trigonal prism (D₃h symmetry); symmetry breaking pattern T_d → C₃/C₁ mirrors spontaneous symmetry breaking in gauge theories; no golden Author: Andrew Stewart Caldin, Independent Researcher, UK. Part of the E8 Intelligence Research series. Platform: e8intelligence.com

Zenodo (CERN European Organization for Nuclear Research)
Advanced NMR Techniques and Applications
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