Photoconversion Behavior of a ZnO/Graphite Solar Cell

Abstract This work assembled dye solar cells by replacing platinum with graphite on indium tin oxide (ITO). First, the device was tested only on the ITO; afterward, graphite was placed on the ITO and evaluated as a counter electrode in the cell. The results showed that the presence of graphite increased the incident photocurrent conversion (IPCE) of the cell. The electrode used was a combination of zinc oxide with 4% bismuth, and characterization of the film had high reflectance in the visible region, a thickness of around 1.47 μm, and a crystallite size of around 38.5 nm. The addition of graphite as a counter electrode increased the cell efficiency by 10 times, driven by an increase in current density from 0.02 to 1.2 mA/cm and in IPCE from 0.04 to 2.26%.

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Publication Details

Journal
ACS Omega
Published
2026-11-06
DOI
https://doi.org/10.1021/acsomega.6c06228
Primary Topic
TiO2 Photocatalysis and Solar Cells
Type
article
Field-Weighted Citation Impact
0.00

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article

Photoconversion Behavior of a ZnO/Graphite Solar Cell

Francisco Nivaldo Aguiar Freire, Francisco Marcone Lima, Vanja Fontenele Nunes, Carla Freitas de Andrade et al.
ACS Omega
TiO2 Photocatalysis and Solar Cells
article

Photoconversion Behavior of a ZnO/Graphite Solar Cell

Francisco Nivaldo Aguiar Freire, Francisco Marcone Lima, Vanja Fontenele Nunes, Carla Freitas de Andrade, A. S. B. Sombra
article en

Abstract

Abstract This work assembled dye solar cells by replacing platinum with graphite on indium tin oxide (ITO). First, the device was tested only on the ITO; afterward, graphite was placed on the ITO and evaluated as a counter electrode in the cell. The results showed that the presence of graphite increased the incident photocurrent conversion (IPCE) of the cell. The electrode used was a combination of zinc oxide with 4% bismuth, and characterization of the film had high reflectance in the visible region, a thickness of around 1.47 μm, and a crystallite size of around 38.5 nm. The addition of graphite as a counter electrode increased the cell efficiency by 10 times, driven by an increase in current density from 0.02 to 1.2 mA/cm and in IPCE from 0.04 to 2.26%.

ACS Omega
Instituto Tecnológico de Aeronáutica (BR), Universidade Federal do Ceará (BR)
Coordenação de Aperfeiçoamento de Pessoal de Nível Superior, Ministério da Ciência, Tecnologia e Inovação, Conselho Nacional de Desenvolvimento Científico e Tecnológico, Sistema de Laboratórios em Nanotecnologias, Universidade Federal de Viçosa
Affordable and clean energy
Openalex Percentile: Top 35%
TiO2 Photocatalysis and Solar Cells
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