Infrared Spectroscopic Analysis of Changes in the Physicochemical Properties and Hydrocarbon Composition of Used Hydraulic Oil During Operation

The article investigates changes in the physicochemical properties and hydrocarbon composition of used L-HL 46 hydraulic oil during operation, comparing it with fresh oil. The samples were analyzed using GOST methods across 12 parameters. As a result of operation, the kinematic viscosity at 40 °C decreased from 46 to 30.56 mm²/s (approximately 33.6%), the viscosity index decreased from 103 to 90, and the flash point dropped from 226 to 212.9 °C, while the acid number increased from 0.5 to 0.8 mg KOH/g. Infrared spectroscopy revealed an approximately 3% decrease in the content of paraffinic and naphthenic hydrocarbons and the occurrence of mild oxidation, while indicating that the chemical composition of the oil's hydrocarbon base remained unchanged. Treatment with alkali and adsorptive purification using Navbahor bentonite did not affect the principal hydrocarbon composition of the oil, indicating that the used oil can be regenerated and reused.

Authors

Publication Details

Journal
Zenodo (CERN European Organization for Nuclear Research)
Published
2026-11-05
DOI
https://doi.org/10.5281/zenodo.23975135
Primary Topic
Lubricants and Their Additives
Type
article
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article

Infrared Spectroscopic Analysis of Changes in the Physicochemical Properties and Hydrocarbon Composition of Used Hydraulic Oil During Operation

Hotamov Qobul
Zenodo (CERN European Organization for Nuclear Research)
Lubricants and Their Additives
article

Infrared Spectroscopic Analysis of Changes in the Physicochemical Properties and Hydrocarbon Composition of Used Hydraulic Oil During Operation

Hotamov Qobul
article en

Abstract

The article investigates changes in the physicochemical properties and hydrocarbon composition of used L-HL 46 hydraulic oil during operation, comparing it with fresh oil. The samples were analyzed using GOST methods across 12 parameters. As a result of operation, the kinematic viscosity at 40 °C decreased from 46 to 30.56 mm²/s (approximately 33.6%), the viscosity index decreased from 103 to 90, and the flash point dropped from 226 to 212.9 °C, while the acid number increased from 0.5 to 0.8 mg KOH/g. Infrared spectroscopy revealed an approximately 3% decrease in the content of paraffinic and naphthenic hydrocarbons and the occurrence of mild oxidation, while indicating that the chemical composition of the oil's hydrocarbon base remained unchanged. Treatment with alkali and adsorptive purification using Navbahor bentonite did not affect the principal hydrocarbon composition of the oil, indicating that the used oil can be regenerated and reused.

Zenodo (CERN European Organization for Nuclear Research)
Openalex Percentile: Top 24%
Lubricants and Their Additives
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