Percolation of sheared suspensions of attractive hard spheres

We have simulated suspensions of colloidal spheres under shear flow to study the formation of clusters, the percolation transition, and the conductivity of the suspensions. The spheres interact via a steep repulsive core and an optional attractive tail of varying strength. In the steady state, we observe transient clusters in the plane orthogonal to the flow direction, which lead to a decreased percolation threshold. These anisotropic clusters are strongly aligned. They affect the conductivity under shear and occur independently of the geometric connectivity criterion and the attractive strength of the spheres. Attractions lower the percolation threshold, but shear flow counteracts this effect. The alignment of clusters and the anisotropy of the conductivity become non-monotonic for the strongest attraction we studied. The flow-aligned orientation of clusters controls the behavior at weaker shear in that case.

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Publication Details

Journal
The Journal of Chemical Physics
Published
2026-11-04
DOI
https://doi.org/10.1063/5.0355983
Primary Topic
Material Dynamics and Properties
Type
article
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article

Percolation of sheared suspensions of attractive hard spheres

Tanja Schilling, Victor Tänzel, Matthias Müller, Silas Boos
The Journal of Chemical Physics
Material Dynamics and Properties
article

Percolation of sheared suspensions of attractive hard spheres

Tanja Schilling, Victor Tänzel, Matthias Müller, Silas Boos
article en

Abstract

We have simulated suspensions of colloidal spheres under shear flow to study the formation of clusters, the percolation transition, and the conductivity of the suspensions. The spheres interact via a steep repulsive core and an optional attractive tail of varying strength. In the steady state, we observe transient clusters in the plane orthogonal to the flow direction, which lead to a decreased percolation threshold. These anisotropic clusters are strongly aligned. They affect the conductivity under shear and occur independently of the geometric connectivity criterion and the attractive strength of the spheres. Attractions lower the percolation threshold, but shear flow counteracts this effect. The alignment of clusters and the anisotropy of the conductivity become non-monotonic for the strongest attraction we studied. The flow-aligned orientation of clusters controls the behavior at weaker shear in that case.

The Journal of Chemical PhysicsVol. 165(17)
University of Freiburg (DE)
Openalex Percentile: Top 30%
Material Dynamics and Properties
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