Aplicação da equação de Arrhenius na análise cinética da produção de hidrogênio por corrosão alcalina da liga Al-3Mg-0,5Fe

This study investigated the Arrhenius equation applied to hydrogen production through the alkaline corrosion of the Al-3Mg-0.5Fe alloy in NaOH solutions (1, 2, and 4 mol·L⁻¹) at temperatures between 30 and 50 °C. Increasing both temperature and NaOH concentration enhanced H₂ production and flow rate, reaching a maximum of approximately 1,130 mL·g⁻¹·cm⁻² and 15.0 mL·min⁻¹ at 4 mol·L⁻¹ and 50 °C. The results indicate predominant surface reaction control during the initial stages, followed by an increasing influence of mass transfer limitations and corrosion product accumulation.

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Publication Details

Journal
Anais do Encontro Nacional de Pós Graduação
Published
2026-11-04
DOI
https://doi.org/10.66221/2zdthw49
Primary Topic
Hydrogen Storage and Materials
Type
article
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article

Aplicação da equação de Arrhenius na análise cinética da produção de hidrogênio por corrosão alcalina da liga Al-3Mg-0,5Fe

Felipe Bertelli, Marcelo Yamaguti, Wallace Alfredo Travassos
Anais do Encontro Nacional de Pós Graduação
Hydrogen Storage and Materials
article

Aplicação da equação de Arrhenius na análise cinética da produção de hidrogênio por corrosão alcalina da liga Al-3Mg-0,5Fe

Felipe Bertelli, Marcelo Yamaguti, Wallace Alfredo Travassos
article en

Abstract

This study investigated the Arrhenius equation applied to hydrogen production through the alkaline corrosion of the Al-3Mg-0.5Fe alloy in NaOH solutions (1, 2, and 4 mol·L⁻¹) at temperatures between 30 and 50 °C. Increasing both temperature and NaOH concentration enhanced H₂ production and flow rate, reaching a maximum of approximately 1,130 mL·g⁻¹·cm⁻² and 15.0 mL·min⁻¹ at 4 mol·L⁻¹ and 50 °C. The results indicate predominant surface reaction control during the initial stages, followed by an increasing influence of mass transfer limitations and corrosion product accumulation.

Anais do Encontro Nacional de Pós GraduaçãoVol. 10(1)
Universidade Tecnológica Federal do Paraná (BR), Processos - Soluções de Engenharia (Brazil) (BR), Universidade Santa Cecília (BR)
Openalex Percentile: Top 30%
Hydrogen Storage and Materials
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