Adiabatic Variational Principle: Born-Oppenheimer Theory for Emergent Electronic-Order Dynamics

Recent advances in microscopic many-body methods have enabled increasingly accurate descriptions of equilibrium quantum states, yet large-scale simulations of emergent-order dynamics typically rely on phenomenological equations with prescribed free-energy functionals. We introduce the Adiabatic Variational Principle (AVP), a framework for deriving order-parameter dynamics directly from an interacting many-body Hamiltonian. When microscopic relaxation is fast compared with order-parameter evolution, the many-body state follows the collective configuration adiabatically, in analogy with the Born--Oppenheimer separation of electronic and nuclear motion. This assumption makes explicit the adiabatic closure implicit in conventional phase-field descriptions. Each instantaneous order-parameter configuration then defines a constrained quasi-stationary many-body state, and the Lagrange multipliers enforcing these constraints directly provide the thermodynamic forces driving the collective evolution. Nonlinear Mori--Zwanzig projection theory further connects the reversible dynamics to the microscopic algebra of the collective variables and relates dissipation and fluctuations to the eliminated degrees of freedom. Applications to charge- and spin-density-wave dynamics recover Allen--Cahn domain growth, resolve evolving domain networks together with their microscopic electronic structure, and yield generalized Landau--Lifshitz dynamics for itinerant magnetism. The AVP thus provides a solver-independent microscopic foundation for phase-field-like simulations of the nonequilibrium dynamics of emergent electronic order.

Authors

Publication Details

Journal
arXiv (Cornell University)
Published
2026-10-29
DOI
https://doi.org/10.48550/arxiv.2610.40117
Primary Topic
Physics of Superconductivity and Magnetism
Type
preprint
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preprint

Adiabatic Variational Principle: Born-Oppenheimer Theory for Emergent Electronic-Order Dynamics

Yunhao Fan, Gia-Wei Chern, Sankha Subhra Bakshi, Ali Rayat et al.
arXiv (Cornell University)
Physics of Superconductivity and Magnetism
preprint

Adiabatic Variational Principle: Born-Oppenheimer Theory for Emergent Electronic-Order Dynamics

Yunhao Fan, Gia-Wei Chern, Sankha Subhra Bakshi, Ali Rayat, Yang Yang, Ho Jang
preprint en

Abstract

Recent advances in microscopic many-body methods have enabled increasingly accurate descriptions of equilibrium quantum states, yet large-scale simulations of emergent-order dynamics typically rely on phenomenological equations with prescribed free-energy functionals. We introduce the Adiabatic Variational Principle (AVP), a framework for deriving order-parameter dynamics directly from an interacting many-body Hamiltonian. When microscopic relaxation is fast compared with order-parameter evolution, the many-body state follows the collective configuration adiabatically, in analogy with the Born--Oppenheimer separation of electronic and nuclear motion. This assumption makes explicit the adiabatic closure implicit in conventional phase-field descriptions. Each instantaneous order-parameter configuration then defines a constrained quasi-stationary many-body state, and the Lagrange multipliers enforcing these constraints directly provide the thermodynamic forces driving the collective evolution. Nonlinear Mori--Zwanzig projection theory further connects the reversible dynamics to the microscopic algebra of the collective variables and relates dissipation and fluctuations to the eliminated degrees of freedom. Applications to charge- and spin-density-wave dynamics recover Allen--Cahn domain growth, resolve evolving domain networks together with their microscopic electronic structure, and yield generalized Landau--Lifshitz dynamics for itinerant magnetism. The AVP thus provides a solver-independent microscopic foundation for phase-field-like simulations of the nonequilibrium dynamics of emergent electronic order.

arXiv (Cornell University)
Physics of Superconductivity and Magnetism
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Adiabatic Variational Principle: Born-Oppenheimer Theory for Emergent Electronic-Order Dynamics — Yunhao Fan, Gia-Wei Chern, et al. · arXiv (Cornell University) (2026) | TGRS Research Map | TGRS