Numerical study of the free energy monotonicity for the Enskog equation: The thermal relaxation of the dense gas between two parallel plates

The thermal relaxation problem between two parallel plates with the same temperature is investigated, aiming to study the behavior of the free energy of the dense gas described by the Enskog equation. Two types of Enskog equation have been used: one is the Enskog equation with the original Enskog factor, while the other is that with a modified Enskog factor proposed recently in Takata & Takahashi, Phys. Rev. E 111, 065108 (2025). The evaluated free energy is a natural extension of the thermodynamic free energy to the non-equilibrium state. It is observed that this free energy monotonically decreases in time for the modified factor version, while it is not necessarily the case for the original version. Differences are also observed in other quantities in the time evolution, most typically in the density profile.