ON A REMARK OF DE GENNES CONCERNING THREE-DIMENSIONAL POLYELECTROLYTES

This work is inspired by a remark of de Gennes [3] about polyelectrolytes, which are charged polymers. A common model for a polymer is a self-avoiding or self-repelling random walk or Brownian motion. For polyelectrolytes, the repelling potential is the Coulomb potential arising from pairs of charged particles. We show that in the continuous case of a Brownian motion in three dimensions, the spread of the polymer, in particular the radius of gyration of a polyelectrolyte of length T grows linearly with T, up to logarithmic corrections.

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Publication Details

Journal
Journal of Stochastic Analysis
Published
2026-11-01
DOI
https://doi.org/10.31390/josa.7.4.01
Primary Topic
Electrostatics and Colloid Interactions
Type
article
Field-Weighted Citation Impact
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article

ON A REMARK OF DE GENNES CONCERNING THREE-DIMENSIONAL POLYELECTROLYTES

Shiquan Li, Carl Mueller
Journal of Stochastic Analysis
Electrostatics and Colloid Interactions
article

ON A REMARK OF DE GENNES CONCERNING THREE-DIMENSIONAL POLYELECTROLYTES

Shiquan Li, Carl Mueller
article en

Abstract

This work is inspired by a remark of de Gennes [3] about polyelectrolytes, which are charged polymers. A common model for a polymer is a self-avoiding or self-repelling random walk or Brownian motion. For polyelectrolytes, the repelling potential is the Coulomb potential arising from pairs of charged particles. We show that in the continuous case of a Brownian motion in three dimensions, the spread of the polymer, in particular the radius of gyration of a polyelectrolyte of length T grows linearly with T, up to logarithmic corrections.

Journal of Stochastic AnalysisVol. 7(4)
Openalex Percentile: Top 25%
Electrostatics and Colloid Interactions
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ON A REMARK OF DE GENNES CONCERNING THREE-DIMENSIONAL POLYELECTROLYTES — Shiquan Li, Carl Mueller · Journal of Stochastic Analysis (2026) | TGRS Research Map | TGRS