Cobalt‐Catalyzed B─H Alkenylation of 1,2‐Azaborines With Terminal Alkynes
The development of general and efficient strategies for direct transformation of B─H bonds in 1,2‐azaborines remains scarce and challenging. Herein, we report a cobalt‐catalyzed B─H alkenylation reaction of 1,2‐azaborines with terminal alkynes. The method provides a versatile platform for the atom‐economic construction of diverse alkenyl‐substituted 1,2‐azaborines in high yields, with excellent regio‐ and stereoselectivities. This protocol features mild reaction conditions, broad substrate scope, and excellent functional group tolerance.
Authors
- Wen‐Juan Hao (ORCID: https://orcid.org/0000-0002-0646-7192)
- Xin Liu (ORCID: https://orcid.org/0000-0001-9419-7462)
- Zi Yang (ORCID: https://orcid.org/0000-0002-8377-118X)
- Bo Jiang (ORCID: https://orcid.org/0000-0003-3878-515X)
- Ke Chen (ORCID: https://orcid.org/0009-0004-9962-2316)
- Zhi‐Jie Diao
Institutions
- Jiangsu Normal University (CN)
- Changsha Medical University (CN)
Publication Details
- Journal
- Advanced Synthesis & Catalysis
- Published
- 2026-10-13
- DOI
- https://doi.org/10.1002/adsc.70814
- Primary Topic
- Organoboron and organosilicon chemistry
- Type
- article
- Field-Weighted Citation Impact
- 0.00
Funders
- National Natural Science Foundation of China
- Jiangsu Normal University
- Natural Science Foundation of Jiangsu Province
- Basic Research Program of Jiangsu Province