Temperature and Pressure Effects on CO2 Foam Aging Revealed by Multi-Descriptor Optical Analysis and Complementary High-Pressure Evaluation

Abstract Optical methods are widely used to evaluate foam stability, but their signals integrate liquid drainage, phase redistribution, bubble-size evolution, and coalescence, limiting mechanism-specific interpretation. This study applies a measurement-aware, multidescriptor strategy combining bench-scale Turbiscan screening, an independent high-pressure CO2-foam visual-cell campaign, and porous-media core-flood evaluation. At 30, 45, and 60 °C, initial gas entrainment, liquid drainage, apparent optical bubble evolution, foam–liquid boundary migration, regional backscattering variation, and the Turbiscan Stability Index were evaluated. High-pressure CO2-foam performance was independently assessed over 12–22 MPa using maximum foam volume and foam half-life. Increasing temperature enhanced initial gas entrainment but accelerated subsequent structural aging, as indicated by faster drainage, earlier boundary migration, a higher apparent cubic-radius evolution coefficient, and greater cumulative optical variation. The apparent cubic-radius evolution coefficient increased from 1.14 × 105 to 2.27 × 105 μm3·min–1 between 30 and 60 °C. In the high-pressure campaign, increasing target pressure under the adopted density-based charging protocol was associated with higher maximum foam volume and longer half-life, although the adverse effect of elevated temperature remained. Because CO2 inventory, surfactant-stock charge, and ethanol content covaried with target-state CO2 density, this trend is interpreted as a combined pressure–charge/formulation response rather than an isolated thermodynamic pressure effect. At 22 MPa, increasing temperature from 30 to 60 °C reduced the maximum foam volume from approximately 1190 to 865 mL and the half-life from 198 to 125 min. The core-flood experiments provided initial porous-media evidence: CO2/E-1340 foam increased the final oil recovery factor to 53.24%, compared with 40.79% for CO2 flooding and 26.97% for brine flooding. During foam treatment, the differential pressure increased from 0.26 to 2.68 MPa and stabilized at 1.98 MPa after treatment, corresponding to a resistance factor of 10.308 and a residual resistance factor of 7.615. These results extend the bulk-cell and high-pressure screening observations to initial porous-media evidence of increased flow resistance and improved displacement performance under the tested conditions. Broader validation using additional reservoir-fluid systems and multiple core conditions, together with experiments that independently decouple pressure from CO2 inventory, remains necessary before the results can be generalized to formation-specific EOR or CCUS applications.

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Publication Details

Journal
Energy & Fuels
Published
2026-10-13
DOI
https://doi.org/10.1021/acs.energyfuels.6c04168
Primary Topic
Enhanced Oil Recovery Techniques
Type
article
Field-Weighted Citation Impact
0.00

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article

Temperature and Pressure Effects on CO2 Foam Aging Revealed by Multi-Descriptor Optical Analysis and Complementary High-Pressure Evaluation

Fajun Zhao, Jiankang Yun, Qiming Liu, Meng Li et al.
Energy & Fuels
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article

Temperature and Pressure Effects on CO2 Foam Aging Revealed by Multi-Descriptor Optical Analysis and Complementary High-Pressure Evaluation

Fajun Zhao, Jiankang Yun, Qiming Liu, Meng Li, Zian Yang, Keliang Wang, Yong Huang, Yong Liu
article en

Abstract

Abstract Optical methods are widely used to evaluate foam stability, but their signals integrate liquid drainage, phase redistribution, bubble-size evolution, and coalescence, limiting mechanism-specific interpretation. This study applies a measurement-aware, multidescriptor strategy combining bench-scale Turbiscan screening, an independent high-pressure CO2-foam visual-cell campaign, and porous-media core-flood evaluation. At 30, 45, and 60 °C, initial gas entrainment, liquid drainage, apparent optical bubble evolution, foam–liquid boundary migration, regional backscattering variation, and the Turbiscan Stability Index were evaluated. High-pressure CO2-foam performance was independently assessed over 12–22 MPa using maximum foam volume and foam half-life. Increasing temperature enhanced initial gas entrainment but accelerated subsequent structural aging, as indicated by faster drainage, earlier boundary migration, a higher apparent cubic-radius evolution coefficient, and greater cumulative optical variation. The apparent cubic-radius evolution coefficient increased from 1.14 × 105 to 2.27 × 105 μm3·min–1 between 30 and 60 °C. In the high-pressure campaign, increasing target pressure under the adopted density-based charging protocol was associated with higher maximum foam volume and longer half-life, although the adverse effect of elevated temperature remained. Because CO2 inventory, surfactant-stock charge, and ethanol content covaried with target-state CO2 density, this trend is interpreted as a combined pressure–charge/formulation response rather than an isolated thermodynamic pressure effect. At 22 MPa, increasing temperature from 30 to 60 °C reduced the maximum foam volume from approximately 1190 to 865 mL and the half-life from 198 to 125 min. The core-flood experiments provided initial porous-media evidence: CO2/E-1340 foam increased the final oil recovery factor to 53.24%, compared with 40.79% for CO2 flooding and 26.97% for brine flooding. During foam treatment, the differential pressure increased from 0.26 to 2.68 MPa and stabilized at 1.98 MPa after treatment, corresponding to a resistance factor of 10.308 and a residual resistance factor of 7.615. These results extend the bulk-cell and high-pressure screening observations to initial porous-media evidence of increased flow resistance and improved displacement performance under the tested conditions. Broader validation using additional reservoir-fluid systems and multiple core conditions, together with experiments that independently decouple pressure from CO2 inventory, remains necessary before the results can be generalized to formation-specific EOR or CCUS applications.

Energy & Fuels
Daqing Oilfield General Hospital (CN), Northeast Petroleum University (CN)
National Natural Science Foundation of China, Natural Science Foundation of Heilongjiang Province
Openalex Percentile: Top 18%
Enhanced Oil Recovery Techniques
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