Hypervalent Iodine‐Mediated Oxidative Cleavage of Ethylenediamine Derivatives and Its Application to Ring Contraction
Hypervalent iodine‐mediated oxidative cleavage of ethylenediamine derivatives enables direct access to imines from readily available substrates. The method proceeds under mild conditions, tolerates diverse sulfonamides, and is applicable to one‐pot transformations and ring contraction reactions, offering a versatile approach to nitrogen‐containing scaffolds.
Authors
- Kazuki Kawanaka
- Satoshi Minakata (ORCID: https://orcid.org/0000-0001-9619-445X)
- Yota Sakakibara (ORCID: https://orcid.org/0000-0003-2951-8930)
- Daiki Higuchi
- Kei Murakami (ORCID: https://orcid.org/0000-0001-5405-3069)
- Ryo Nakajima
- Takeshi Sugiyama
- Satoshi Matsubara
- Takaya Tomoike
- Wakana Ito
- Kota Hashimoto
Institutions
- Kwansei Gakuin University (JP)
- The University of Osaka (JP)
Publication Details
- Journal
- Advanced Synthesis & Catalysis
- Published
- 2026-10-05
- DOI
- https://doi.org/10.1002/adsc.70772
- Primary Topic
- Oxidative Organic Chemistry Reactions
- Type
- article
- Field-Weighted Citation Impact
- 0.00