Effect of polymerization conditions on film thickness and charge-transfer resistance of phytic acid-doped poly(m-aminophenylboronic acid) film electrode under neutral conditions

In this study, we investigated the effects of polymerization conditions on the film thickness and electrical characteristics of phytic acid-doped poly(m-aminophenylboronic acid) (PA-PAPBA) films under neutral conditions for biosensing applications using an electrochemical method. In particular, polymerization parameters, such as monomer concentration and polymerization time, were varied. As the monomer concentration and the polymerization time increased, the film thickness increased, whereas the charge-transfer resistance of the PA-PAPBA films decreased. These findings indicate that polymerization conditions are important for controlling the thickness and charge-transfer characteristics of the PA-PAPBA films for biosensing.

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Publication Details

Journal
MRS Communications
Published
2026-10-05
DOI
https://doi.org/10.1557/s43579-026-01060-4
Primary Topic
Electrochemical sensors and biosensors
Type
article
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article

Effect of polymerization conditions on film thickness and charge-transfer resistance of phytic acid-doped poly(m-aminophenylboronic acid) film electrode under neutral conditions

Toshiya Sakata, Megumi Inoue
MRS Communications
Electrochemical sensors and biosensors
article

Effect of polymerization conditions on film thickness and charge-transfer resistance of phytic acid-doped poly(m-aminophenylboronic acid) film electrode under neutral conditions

Toshiya Sakata, Megumi Inoue
article en

Abstract

In this study, we investigated the effects of polymerization conditions on the film thickness and electrical characteristics of phytic acid-doped poly(m-aminophenylboronic acid) (PA-PAPBA) films under neutral conditions for biosensing applications using an electrochemical method. In particular, polymerization parameters, such as monomer concentration and polymerization time, were varied. As the monomer concentration and the polymerization time increased, the film thickness increased, whereas the charge-transfer resistance of the PA-PAPBA films decreased. These findings indicate that polymerization conditions are important for controlling the thickness and charge-transfer characteristics of the PA-PAPBA films for biosensing.

MRS Communications
The University of Tokyo (JP)
Openalex Percentile: Top 22%
Electrochemical sensors and biosensors
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Effect of polymerization conditions on film thickness and charge-transfer resistance of phytic acid-doped poly(m-aminophenylboronic acid) film electrode under neutral conditions — Toshiya Sakata, Megumi Inoue · MRS Communications (2026) | TGRS Research Map | TGRS