Synthesis of 2,3′-Azacorrole Dimer via Acid-Catalyzed Oxidative Coupling
Abstract 2,3′-Azacorrole dimer was synthesized via regioselective oxidative coupling of 10-azacorrole by p-chloranil in the presence of trifluoroacetic acid in moderate yield. The structures of all the products were characterized thoroughly by NMR and HRMS. The UV-Vis absorption spectra show obvious bathochromic shifts of both the Soret band and Q bands, along with a marked increase in the absorbance of the Q bands.
Authors
- Guangyuan Luo
- Zhonglan Wei
- Guoru Chen
- Xiaofang Li
Institutions
- Hunan University of Science and Technology (CN)
Publication Details
- Journal
- Russian Journal of General Chemistry
- Published
- 2026-09-30
- DOI
- https://doi.org/10.1134/s1070363226603170
- Primary Topic
- Radical Photochemical Reactions
- Type
- article
- Field-Weighted Citation Impact
- 0.00