Electrochemically Induced Regio‐ and Stereoselective ( E )‐β‐C(sp 2 )─H Alkoxycarbonylation of Enamides With Carbazates
Herein, we disclosed an electrochemically induced alkoxycarbonylation of enamides with carbazates under metal‐free and peroxide‐free reaction conditions, which provided a green protocol for constructing enol esters, exhibiting excellent regioselectivity and mainly affording products in the E ‐configuration. Mechanistically, a free alkoxycarbonyl radical pathway was involved in this approach.
Authors
- Ling Yang (ORCID: https://orcid.org/0000-0003-4425-9770)
- Haiqing Luo (ORCID: https://orcid.org/0000-0003-2159-8403)
- Xiaolan Li
- Yiyan Lin
- Guisheng Chen
- Xuzhong Luo
- Yucheng Yang
Institutions
- Gannan Normal University (CN)
Publication Details
- Journal
- Advanced Synthesis & Catalysis
- Published
- 2026-09-29
- DOI
- https://doi.org/10.1002/adsc.70785
- Primary Topic
- Radical Photochemical Reactions
- Type
- article
- Field-Weighted Citation Impact
- 0.00