Sr 2 [CN 2 ][NH] – A Carbodiimide Imide
The novel mixed anionic compound Sr 2 [CN 2 ][NH] crystallizes as colorless transparent platelets in the orthorhombic space group Pnma . It contains carbodiimide anions alongside imide anions and shares structural similarities with the respective binary compounds strontium carbodiimide, α – and β –Sr[CN 2 ], and strontium imide, β –Sr[NH]. Raman spectroscopy clearly confirms the presence of carbodiimide and imide ions as corroborated by simulations based on DFT‐derived phonons.
Authors
- Rainer Niewa (ORCID: https://orcid.org/0000-0002-2633-7109)
- Robert U. Stelzer
- Guowei Sun (ORCID: https://orcid.org/0009-0005-9373-3944)
Institutions
- University of Stuttgart (DE)
Publication Details
- Journal
- Zeitschrift für anorganische und allgemeine Chemie
- Published
- 2026-09-29
- DOI
- https://doi.org/10.1002/zaac.70203
- Primary Topic
- Inorganic Chemistry and Materials
- Type
- article
- Field-Weighted Citation Impact
- 0.00