New features of BDF since 2020

The Beijing Density Functional (BDF) program package, with a history of over 30 years, is primarily characterized by its inclusion of the full range of relativistic Hamiltonians (one-, two-, quasi-four-, effective-four-, and four-component, as well as quantum electrodynamics) alongside fully symmetry-adapted density functional theory (DFT), time-dependent (TD) DFT, and single/multi-reference wave function theories (WFTs) for electronic structures and response properties of molecular systems. New features of BDF since its last summary [Zhang et al., J. Chem. Phys. 152, 064113 (2020)] include approximate treatments of relativistic effects, improved SCF solvers, implicit and explicit solvation models, enhanced TDDFT, new multi-reference WFT for strong correlation, and analytic gradients, Hessians, and nonadiabatic coupling matrix elements for both ground and excited states, as well as extensions to various spectroscopies. These developments have transformed BDF into a comprehensive and efficient electronic structure program well-suited for real-world applications.

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Publication Details

Journal
The Journal of Chemical Physics
Published
2026-09-28
DOI
https://doi.org/10.1063/5.0349838
Primary Topic
Advanced Chemical Physics Studies
Type
article
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New features of BDF since 2020

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The Journal of Chemical Physics
Advanced Chemical Physics Studies
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New features of BDF since 2020

Zhong‐Jun Zhou, Ning Zhang, Bingbing Suo, Wenjian Liu, Haisheng Ren, Zikuan Wang, Qixin Chen, Zexing Qu, Yibo Lei, Yang Guo, Hao Wang, Guanlin Song, Wenli Zou, Yong Zhang, Jun Gao, Langyuan Qin
article en

Abstract

The Beijing Density Functional (BDF) program package, with a history of over 30 years, is primarily characterized by its inclusion of the full range of relativistic Hamiltonians (one-, two-, quasi-four-, effective-four-, and four-component, as well as quantum electrodynamics) alongside fully symmetry-adapted density functional theory (DFT), time-dependent (TD) DFT, and single/multi-reference wave function theories (WFTs) for electronic structures and response properties of molecular systems. New features of BDF since its last summary [Zhang et al., J. Chem. Phys. 152, 064113 (2020)] include approximate treatments of relativistic effects, improved SCF solvers, implicit and explicit solvation models, enhanced TDDFT, new multi-reference WFT for strong correlation, and analytic gradients, Hessians, and nonadiabatic coupling matrix elements for both ground and excited states, as well as extensions to various spectroscopies. These developments have transformed BDF into a comprehensive and efficient electronic structure program well-suited for real-world applications.

The Journal of Chemical PhysicsVol. 165(12)
Shandong University (CN), Jilin University (CN), Huazhong Agricultural University (CN), Sichuan University (CN), Northwest University (CN), Hongzhiwei Technology (China) (CN), Key Laboratory of Synthetic and Natural Functional Molecular Chemistry, Ministry of Education (CN)
Openalex Percentile: Top 14%
Advanced Chemical Physics Studies
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