Demonstrations of Photochemical Reactions Using Methylene Blue and Ascorbic Acid

Abstract Photochemical processes are important in nature and technology but can be difficult for students to conceptualize and visualize. In this study, a visible-light-responsive photochromic system comprising methylene blue (MB+) and ascorbic acid (AsA) is used for classroom demonstrations of photochemical reactions. The aqueous system operates at room temperature and exhibits repeatable, reversible coloration under 405 nm blue–violet light, followed by spontaneous decolorization. Four core demonstrations and one optional extension are presented: (1) basic color change, (2) two-dimensional pattern formation, (3) effects of light wavelength and shielding, (4) effects of chemical conditions, and (5) visualization of solution flow using transient photogenerated color.

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Publication Details

Journal
Journal of Chemical Education
Published
2026-09-21
DOI
https://doi.org/10.1021/acs.jchemed.6c00435
Primary Topic
Various Chemistry Research Topics
Type
article
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article

Demonstrations of Photochemical Reactions Using Methylene Blue and Ascorbic Acid

Masayuki Inoue, 隆良 木村, Masatada Matsuoka, Takahiro Suzuki et al.
Journal of Chemical Education
Various Chemistry Research Topics
article

Demonstrations of Photochemical Reactions Using Methylene Blue and Ascorbic Acid

Masayuki Inoue, 隆良 木村, Masatada Matsuoka, Takahiro Suzuki, Kanon Ie, Yuika Shimizu
article en

Abstract

Abstract Photochemical processes are important in nature and technology but can be difficult for students to conceptualize and visualize. In this study, a visible-light-responsive photochromic system comprising methylene blue (MB+) and ascorbic acid (AsA) is used for classroom demonstrations of photochemical reactions. The aqueous system operates at room temperature and exhibits repeatable, reversible coloration under 405 nm blue–violet light, followed by spontaneous decolorization. Four core demonstrations and one optional extension are presented: (1) basic color change, (2) two-dimensional pattern formation, (3) effects of light wavelength and shielding, (4) effects of chemical conditions, and (5) visualization of solution flow using transient photogenerated color.

Journal of Chemical Education
Tokyo University of Science (JP), Fukuoka University (JP)
Openalex Percentile: Top 13%
Various Chemistry Research Topics
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Demonstrations of Photochemical Reactions Using Methylene Blue and Ascorbic Acid — Masayuki Inoue, 隆良 木村, et al. · Journal of Chemical Education (2026) | TGRS Research Map | TGRS