Mechanical Behavior of Chopped Fiber-Reinforced Elastomeric Polyurea Foams

Abstract Elastomeric foams have received significant attention for impact mitigation in civilian and military applications. At the forefront of these materials are polyurea foams, which have demonstrated superior energy dissipation capabilities at reduced weight penalties under single- and repeated-impact loading over a wide range of projectile velocities. In this study, an innovative class of reinforced elastomeric polyurea foams is introduced by incorporating high-performance fibers, including Kevlar, Vectran, and Dyneema, into the foam slurry. A modified manufacturing process produced 30 cm × 30 cm foam sheets, from which cuboid specimens were extracted using an oscillating tangential knife. These specimens were subjected to quasi-static compression loading at a rate of 50 mm/min to 78% strain, and the testing accompanied by full-field digital image correlation to characterize deformation and strain localization. The results reveal a pronounced hygro-mechanical sensitivity in Kevlar-reinforced foams, which lessens their effective mechanical contribution. In contrast, Vectran- and Dyneema-reinforced foams exhibited substantial enhancements in mechanical response, including increases of more than 150% in the elastic modulus, 115% in plateau stress, and 70% in energy absorption, respectively, relative to the unreinforced baseline. These findings demonstrate the feasibility of tailoring the compressive response and energy-absorption characteristics of polyurea foams through chopped-fiber reinforcement, introducing a class of lightweight ballistic foams suitable for applications ranging from protective sports equipment to energy-absorbing components in armored systems and sandwich structures.

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Publication Details

Journal
ACS Applied Polymer Materials
Published
2026-09-21
DOI
https://doi.org/10.1021/acsapm.6c03405
Primary Topic
Structural Response to Dynamic Loads
Type
article
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Mechanical Behavior of Chopped Fiber-Reinforced Elastomeric Polyurea Foams

George Youssef, Sophia Benkirane
ACS Applied Polymer Materials
Structural Response to Dynamic Loads
article

Mechanical Behavior of Chopped Fiber-Reinforced Elastomeric Polyurea Foams

George Youssef, Sophia Benkirane
article en

Abstract

Abstract Elastomeric foams have received significant attention for impact mitigation in civilian and military applications. At the forefront of these materials are polyurea foams, which have demonstrated superior energy dissipation capabilities at reduced weight penalties under single- and repeated-impact loading over a wide range of projectile velocities. In this study, an innovative class of reinforced elastomeric polyurea foams is introduced by incorporating high-performance fibers, including Kevlar, Vectran, and Dyneema, into the foam slurry. A modified manufacturing process produced 30 cm × 30 cm foam sheets, from which cuboid specimens were extracted using an oscillating tangential knife. These specimens were subjected to quasi-static compression loading at a rate of 50 mm/min to 78% strain, and the testing accompanied by full-field digital image correlation to characterize deformation and strain localization. The results reveal a pronounced hygro-mechanical sensitivity in Kevlar-reinforced foams, which lessens their effective mechanical contribution. In contrast, Vectran- and Dyneema-reinforced foams exhibited substantial enhancements in mechanical response, including increases of more than 150% in the elastic modulus, 115% in plateau stress, and 70% in energy absorption, respectively, relative to the unreinforced baseline. These findings demonstrate the feasibility of tailoring the compressive response and energy-absorption characteristics of polyurea foams through chopped-fiber reinforcement, introducing a class of lightweight ballistic foams suitable for applications ranging from protective sports equipment to energy-absorbing components in armored systems and sandwich structures.

ACS Applied Polymer Materials
San Diego State University (US)
Affordable and clean energy
Openalex Percentile: Top 17%
Structural Response to Dynamic Loads
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Mechanical Behavior of Chopped Fiber-Reinforced Elastomeric Polyurea Foams — George Youssef, Sophia Benkirane · ACS Applied Polymer Materials (2026) | TGRS Research Map | TGRS