Cassiterite U–Pb geochronology: A framework for tin provenance in the Bronze Age world

The origin of Bronze Age tin is one of the most compelling mysteries in global archaeology. A number of studies were carried out to identify fingerprints to determine tin sources, but all failed to suit the contexts of Bronze Age China. This study provides the first comprehensive provenance analysis of the tin ore utilized during the Shang dynasty of China. Using U–Pb dating analysis on cassiterite grains surviving in various contexts including primary smelting site, metal resource hoard, and bronze casting workshop, this study demonstrates that cassiterite materials from the Great Hinggan Range polymetallic belt, Northeast China, were transported to the Middle Huai River region over 1,500 km to the south for tin bronze production during the Middle Shang period. This finding reveals a long-distance, continental-scale metal circulation system comparable to contemporaneous tin supply networks across the world, extending the concept of “bronzization”, the Bronze Age as premodern globalization, into East Asia. It also establishes a methodological framework for resolving the tin provenance questions of Bronze Age China and beyond.

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Publication Details

Journal
Proceedings of the National Academy of Sciences
Published
2026-09-21
DOI
https://doi.org/10.1073/pnas.2625071123
Primary Topic
Mineralogy and Gemology Studies
Type
article
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Cassiterite U–Pb geochronology: A framework for tin provenance in the Bronze Age world

Richen Zhong, Jianli Chen, Siran Liu, Botao Cai et al.
Proceedings of the National Academy of Sciences
Mineralogy and Gemology Studies
article

Cassiterite U–Pb geochronology: A framework for tin provenance in the Bronze Age world

Richen Zhong, Jianli Chen, Siran Liu, Botao Cai, Zhenfei Sun, Chenyuan Li, Yanxiang Li, Wei Chen, Lixin Wang, Xiaolin He
article en

Abstract

The origin of Bronze Age tin is one of the most compelling mysteries in global archaeology. A number of studies were carried out to identify fingerprints to determine tin sources, but all failed to suit the contexts of Bronze Age China. This study provides the first comprehensive provenance analysis of the tin ore utilized during the Shang dynasty of China. Using U–Pb dating analysis on cassiterite grains surviving in various contexts including primary smelting site, metal resource hoard, and bronze casting workshop, this study demonstrates that cassiterite materials from the Great Hinggan Range polymetallic belt, Northeast China, were transported to the Middle Huai River region over 1,500 km to the south for tin bronze production during the Middle Shang period. This finding reveals a long-distance, continental-scale metal circulation system comparable to contemporaneous tin supply networks across the world, extending the concept of “bronzization”, the Bronze Age as premodern globalization, into East Asia. It also establishes a methodological framework for resolving the tin provenance questions of Bronze Age China and beyond.

Proceedings of the National Academy of SciencesVol. 123(40)
King University (US), Peking University (CN), State Administration of Cultural Heritage (CN), China University of Geosciences (Beijing) (CN), Wuhan University (CN), Institute of Archaeology (CN)
Openalex Percentile: Top 14%
Mineralogy and Gemology Studies
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Cassiterite U–Pb geochronology: A framework for tin provenance in the Bronze Age world — Richen Zhong, Jianli Chen, et al. · Proceedings of the National Academy of Sciences (2026) | TGRS Research Map | TGRS