Quantitative phase-field simulation of dendrite growth in rapidly solidifying WE43 magnesium alloy

In the additive manufacturing of magnesium alloys, layer-by-layer melting and rapid cooling are the core process characteristics; the solute trapping and drag effects significantly influence dendrite growth and final microstructure. This study develops a quantitative phase-field model incorporating a modified anti-solute trapping term that is decoupled from the interface width to investigate the solute drag, temperature gradient ( G ), pulling velocity ( V p ), and sixfold-symmetric anisotropy intensity in dendrite growth during rapid directional solidification of WE43 magnesium alloy. Results show that complete solute drag reduces the peak solute concentration between dendrites by approximately 30%, effectively mitigating microsegregation and delaying morphological instability of the flat interface. Increasing G and V p drives a microstructural transition from dendritic to cellular crystals, causing the dendrite growth direction to shift from the preferential crystallographic orientation toward the heat flux direction, such that the growth angle θ decreases monotonically. As the anisotropy intensity increases, secondary dendrite arms nucleate earlier and side branches become more developed; this effect is particularly pronounced under low temperature gradients. A clear relationship exists between the primary dendrite arm spacing λ d and the process parameters: λ d ∝ G − 1 / 2 V p − 1 / 4 . High temperature gradients enhance directional heat conduction, while high pulling velocity increase interfacial undercooling and reduce the thickness of the solute diffusion boundary layer; together, these factors promote refinement of the dendrite array. This study elucidates the intrinsic mechanisms of dendrite growth under rapid solidification conditions and provides a theoretical basis for precise microstructural design in magnesium alloy additive manufacturing.

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Publication Details

Journal
Computational Materials Science
Published
2026-09-18
DOI
https://doi.org/10.1016/j.commatsci.2026.115086
Primary Topic
Solidification and crystal growth phenomena
Type
article
Field-Weighted Citation Impact
0.00

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article

Quantitative phase-field simulation of dendrite growth in rapidly solidifying WE43 magnesium alloy

W. Chen, Xiaomin Yang, Yuhong Zhao, Enze Wang
Computational Materials Science
Solidification and crystal growth phenomena
article

Quantitative phase-field simulation of dendrite growth in rapidly solidifying WE43 magnesium alloy

W. Chen, Xiaomin Yang, Yuhong Zhao, Enze Wang
article en

Abstract

In the additive manufacturing of magnesium alloys, layer-by-layer melting and rapid cooling are the core process characteristics; the solute trapping and drag effects significantly influence dendrite growth and final microstructure. This study develops a quantitative phase-field model incorporating a modified anti-solute trapping term that is decoupled from the interface width to investigate the solute drag, temperature gradient ( G ), pulling velocity ( V p ), and sixfold-symmetric anisotropy intensity in dendrite growth during rapid directional solidification of WE43 magnesium alloy. Results show that complete solute drag reduces the peak solute concentration between dendrites by approximately 30%, effectively mitigating microsegregation and delaying morphological instability of the flat interface. Increasing G and V p drives a microstructural transition from dendritic to cellular crystals, causing the dendrite growth direction to shift from the preferential crystallographic orientation toward the heat flux direction, such that the growth angle θ decreases monotonically. As the anisotropy intensity increases, secondary dendrite arms nucleate earlier and side branches become more developed; this effect is particularly pronounced under low temperature gradients. A clear relationship exists between the primary dendrite arm spacing λ d and the process parameters: λ d ∝ G − 1 / 2 V p − 1 / 4 . High temperature gradients enhance directional heat conduction, while high pulling velocity increase interfacial undercooling and reduce the thickness of the solute diffusion boundary layer; together, these factors promote refinement of the dendrite array. This study elucidates the intrinsic mechanisms of dendrite growth under rapid solidification conditions and provides a theoretical basis for precise microstructural design in magnesium alloy additive manufacturing.

Computational Materials ScienceVol. 275
Collaborative Innovation Center of Chemistry for Energy Materials (CN), Liaoning Academy of Materials, University of Science and Technology Beijing (CN)
National Natural Science Foundation of China
Openalex Percentile: Top 24%
Solidification and crystal growth phenomena
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