Relaxing bulk modulus in water: Evidence from computer simulation of instantaneous compression

Water demonstrates numerous anomalies. One of them is the extremely large strength of positive sound dispersion (PSD), which means that the frequency dependent speed of sound strongly exceeds the hydrodynamics one. While in simple atomic melts the strength of PSD is of the order of dozen percents, in molecular liquids it is up to $50 \\%$, it reaches as much as $200 \\%$ in water. The origin of such enormous PSD in water is discussed in the present paper. In the framework of molecular simulation methods it is shown that large PSD of water and supercooled silicon (two examples of anomalous liquids) is related to presence of slowly relaxing processes in such liquids which lead to strong frequency dependence of the bulk modulus.

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Publication Details

Journal
Journal of Physics Condensed Matter
Published
2026-09-17
DOI
https://doi.org/10.1088/1361-648x/aea959
Primary Topic
Material Dynamics and Properties
Type
article
Field-Weighted Citation Impact
0.00

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article

Relaxing bulk modulus in water: Evidence from computer simulation of instantaneous compression

В. В. Бражкин, Yury D. Fomin
Journal of Physics Condensed Matter
Material Dynamics and Properties
article

Relaxing bulk modulus in water: Evidence from computer simulation of instantaneous compression

В. В. Бражкин, Yury D. Fomin
article en

Abstract

Water demonstrates numerous anomalies. One of them is the extremely large strength of positive sound dispersion (PSD), which means that the frequency dependent speed of sound strongly exceeds the hydrodynamics one. While in simple atomic melts the strength of PSD is of the order of dozen percents, in molecular liquids it is up to $50 \%$, it reaches as much as $200 \%$ in water. The origin of such enormous PSD in water is discussed in the present paper. In the framework of molecular simulation methods it is shown that large PSD of water and supercooled silicon (two examples of anomalous liquids) is related to presence of slowly relaxing processes in such liquids which lead to strong frequency dependence of the bulk modulus.

Journal of Physics Condensed Matter
Institute for High Pressure Physics (RU)
Russian Science Foundation
Clean water and sanitation
Openalex Percentile: Top 25%
Material Dynamics and Properties
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