Giant Magnetization Enhancement at the Ultrathin Limit of an Orthoferrite

ABSTRACT Low‐dimensional magnetic systems have received significant interest due to their high scalability and energy efficiency for future electromagnetic applications. However, low‐dimensional magnetism at finite temperature is subject to Mermin–Wagner fluctuations, which make its realization highly challenging. Here, we propose structural modulation in the thin‐film structure of an orthoferrite system to achieve a high low‐dimensional magnetic response at room temperature. ErFeO 3 epitaxial thin film with atomically precise thickness control demonstrates that the magnetic response at 300 K can be significantly enhanced compared to its bulk counterpart. The magnetic response reaches its maximum value of 3.7 µ B /f.u. for the 2 nm‐thick epitaxial film. The characteristic domain structure resulting from epitaxial strain and orbital reconstruction at the surface, both arising from the thin film geometry, has been proposed as the microscopic origin of the giant magnetization enhancement. We show that magnetic ordering can indeed be realized in the 2D limit, with deliberate structural control of orthoferrite systems.

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Publication Details

Journal
Advanced Functional Materials
Published
2026-09-16
DOI
https://doi.org/10.1002/adfm.78476
Primary Topic
Multiferroics and related materials
Type
article
Field-Weighted Citation Impact
0.00

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article

Giant Magnetization Enhancement at the Ultrathin Limit of an Orthoferrite

Heemin Lee, Heung‐Sik Kim, Seung Gyo Jeong, Woo‐Suk Noh et al.
Advanced Functional Materials
Multiferroics and related materials
article

Giant Magnetization Enhancement at the Ultrathin Limit of an Orthoferrite

Heemin Lee, Heung‐Sik Kim, Seung Gyo Jeong, Woo‐Suk Noh, J OH, Yeonkyu Lee, Woo Seok Choi, Jun‐Sik Lee, Cheng‐Tai Kuo, Sehwan Song, Si Won Kim, Chanyoung Lee, Sungkyun Park, S. Choi, Sang Ho Oh, Valeria Lauter, Jeehoon Kim, Yaolong Xing, Hong Hyun Jeon, Seyoung Kwon, Jaeha Choi
article en

Abstract

ABSTRACT Low‐dimensional magnetic systems have received significant interest due to their high scalability and energy efficiency for future electromagnetic applications. However, low‐dimensional magnetism at finite temperature is subject to Mermin–Wagner fluctuations, which make its realization highly challenging. Here, we propose structural modulation in the thin‐film structure of an orthoferrite system to achieve a high low‐dimensional magnetic response at room temperature. ErFeO 3 epitaxial thin film with atomically precise thickness control demonstrates that the magnetic response at 300 K can be significantly enhanced compared to its bulk counterpart. The magnetic response reaches its maximum value of 3.7 µ B /f.u. for the 2 nm‐thick epitaxial film. The characteristic domain structure resulting from epitaxial strain and orbital reconstruction at the surface, both arising from the thin film geometry, has been proposed as the microscopic origin of the giant magnetization enhancement. We show that magnetic ordering can indeed be realized in the 2D limit, with deliberate structural control of orthoferrite systems.

Advanced Functional Materials
Pohang University of Science and Technology (KR), Oak Ridge National Laboratory (US), Kangwon National University (KR), SLAC National Accelerator Laboratory (US), Korea Energy Economics Institute (KR), Korea Institute of Energy Research (KR), Korea Foundation for Max Planck POSTECH (KR), Pusan National University (KR), Sungkyunkwan University (KR)
U.S. Department of Energy, National Research Foundation, Pohang University of Science and Technology, National Research Foundation of Korea, Ministry of Education, Science and Technology, Ministry of Science and ICT, South Korea, Office of Science, Basic Energy Sciences, Oak Ridge National Laboratory, SLAC National Accelerator Laboratory
Affordable and clean energy
Openalex Percentile: Top 28%
Multiferroics and related materials
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