Stereocomplex-Enhanced Shear Viscosity of PLA-PEG-PLA Amphiphilic Triblock Copolymers

Abstract Drag-reducing agents have been widely used in hydraulic fracturing processes to conserve energy. However, most of them are not biodegradable, thus posing a threat to ecosystems. In this study, we synthesized a series of biodegradable copolymers, PLLA-PEG-PLLA and PDLA-PEG-PDLA, and prepared their stereocomplexes. Shear viscosity measurements were conducted to study how the polymer structures and stereocomplexation lead to different rheological properties in a brine solution.

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Publication Details

Journal
Polymer science & technology.
Published
2026-09-15
DOI
https://doi.org/10.1021/polymscitech.6c00055
Primary Topic
Hydraulic Fracturing and Reservoir Analysis
Type
article
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article

Stereocomplex-Enhanced Shear Viscosity of PLA-PEG-PLA Amphiphilic Triblock Copolymers

Hailey Tran, Hootan Roshandel, Advait Holkar, Hyuk‐Joon Jung et al.
Polymer science & technology.
Hydraulic Fracturing and Reservoir Analysis
article

Stereocomplex-Enhanced Shear Viscosity of PLA-PEG-PLA Amphiphilic Triblock Copolymers

Hailey Tran, Hootan Roshandel, Advait Holkar, Hyuk‐Joon Jung, Samanvaya Srivastava, Connor F. Gallin, Paula L. Diaconescu, Jeffery A. Byers, Shijie Deng, Yifan Li, Qijia Zhou, Kimberly Vasquez, Carl Aften, Brandon Van
article en

Abstract

Abstract Drag-reducing agents have been widely used in hydraulic fracturing processes to conserve energy. However, most of them are not biodegradable, thus posing a threat to ecosystems. In this study, we synthesized a series of biodegradable copolymers, PLLA-PEG-PLLA and PDLA-PEG-PDLA, and prepared their stereocomplexes. Shear viscosity measurements were conducted to study how the polymer structures and stereocomplexation lead to different rheological properties in a brine solution.

Polymer science & technology.
Boston College (US), University of California, San Francisco (US), University of California System (US), Technology Holding (United States) (US), Clinical Research Solutions (US), University of California, Berkeley (US)
Openalex Percentile: Top 20%
Hydraulic Fracturing and Reservoir Analysis
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Stereocomplex-Enhanced Shear Viscosity of PLA-PEG-PLA Amphiphilic Triblock Copolymers — Hailey Tran, Hootan Roshandel, et al. · Polymer science & technology. (2026) | TGRS Research Map | TGRS