Chirality enhances diffusion in disordered environments

Chirality, a systematic rotational bias in the motion of a particle, arises in a wide range of physical and biological systems, from charged colloids in magnetic fields to swimming bacteria near surfaces. While its effects in homogeneous environments are well understood, the interplay between chirality and structural disorder has remained largely unexplored. Here, we investigate the chiral random walk on two-dimensional percolation clusters above the percolation threshold, combining numerical simulations with an analytically tractable annealed-disorder approximation. We find that the long-time diffusion coefficient depends non-monotonically on both the chirality parameter and the obstacle density: for every obstacle density above the percolation threshold, there exists an optimal chirality that enhances diffusion relative to the achiral walk. We show that the optimal chirality is set by an edge-adhering mechanism: maximum diffusion is achieved when the persistence length of the wall-adhering motion matches half the typical obstacle cluster perimeter. This yields a closed-form prediction for the optimal chirality in terms of geometric properties of the medium alone, which we verify across the full range of obstacle densities studied. The enhancement extends to first-passage statistics, where chirality shortens typical search times at strong disorder while lengthening them at weak disorder, with direct implications for biological navigation in disordered environments.

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Publication Details

Journal
The Journal of Chemical Physics
Published
2026-09-28
DOI
https://doi.org/10.1063/5.0352851
Primary Topic
Micro and Nano Robotics
Type
article
Field-Weighted Citation Impact
0.00

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article

Chirality enhances diffusion in disordered environments

Erik Kalz, Jan Wójcik, Ralf Metzler, Joshua Uhlig
The Journal of Chemical Physics
Micro and Nano Robotics
article

Chirality enhances diffusion in disordered environments

Erik Kalz, Jan Wójcik, Ralf Metzler, Joshua Uhlig
article en

Abstract

Chirality, a systematic rotational bias in the motion of a particle, arises in a wide range of physical and biological systems, from charged colloids in magnetic fields to swimming bacteria near surfaces. While its effects in homogeneous environments are well understood, the interplay between chirality and structural disorder has remained largely unexplored. Here, we investigate the chiral random walk on two-dimensional percolation clusters above the percolation threshold, combining numerical simulations with an analytically tractable annealed-disorder approximation. We find that the long-time diffusion coefficient depends non-monotonically on both the chirality parameter and the obstacle density: for every obstacle density above the percolation threshold, there exists an optimal chirality that enhances diffusion relative to the achiral walk. We show that the optimal chirality is set by an edge-adhering mechanism: maximum diffusion is achieved when the persistence length of the wall-adhering motion matches half the typical obstacle cluster perimeter. This yields a closed-form prediction for the optimal chirality in terms of geometric properties of the medium alone, which we verify across the full range of obstacle densities studied. The enhancement extends to first-passage statistics, where chirality shortens typical search times at strong disorder while lengthening them at weak disorder, with direct implications for biological navigation in disordered environments.

The Journal of Chemical PhysicsVol. 165(12)
University of Potsdam (DE), University of Gdańsk (PL)
Deutsche Forschungsgemeinschaft, Narodowe Centrum Nauki
Life below water
Openalex Percentile: Top 23%
Micro and Nano Robotics
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Chirality enhances diffusion in disordered environments — Erik Kalz, Jan Wójcik, et al. · The Journal of Chemical Physics (2026) | TGRS Research Map | TGRS