Deformable precipitates locally modify fault-mediated plasticity for strength-ductility synergy

Precipitates in structural alloys are conventionally understood as passive obstacles to dislocation motion. Here we show that semi-coherent hexagonal close-packed precipitates in a low-stacking-fault-energy Ni50Co30Ru20 multi-principal element alloy cooperate with planar-fault plasticity in the face-centered cubic matrix. In-situ neutron diffraction, high-resolution electron microscopy, and first-principles calculations reveal that these precipitates interact with and locally modify Shockley-partial-mediated fault structures, are associated with confined, deformation-related interfacial stacking rearrangement, and generate heterogeneous stress fields that sustain work hardening. Phase-resolved diffraction shows that the precipitates yield at an applied stress of ∼1020 MPa and that the load they carry directly is bounded at ∼6–10% of the yield strength, so their contribution mainly acts through the precipitate-matrix interfaces, resulting in a tensile strength of 1038 MPa and 39% uniform elongation. These findings establish a design strategy: coupling low fault energy with deformable phase heterogeneity amplifies planar-fault-mediated strain hardening.Impact statementSemi-coherent precipitates interact with and locally modify planar-fault plasticity, accommodating interfacial rearrangements, and sustaining heterogeneous stress fields, suggesting a design strategy for strong and ductile alloys.

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Publication Details

Journal
Materials Research Letters
Published
2026-09-13
DOI
https://doi.org/10.1080/21663831.2026.2730519
Primary Topic
High Entropy Alloys Studies
Type
article
Field-Weighted Citation Impact
0.00

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article

Deformable precipitates locally modify fault-mediated plasticity for strength-ductility synergy

Wei Xiong, Yuntian Zhu, Muhammad Naeem, Xun‐Li Wang et al.
Materials Research Letters
High Entropy Alloys Studies
article

Deformable precipitates locally modify fault-mediated plasticity for strength-ductility synergy

Wei Xiong, Yuntian Zhu, Muhammad Naeem, Xun‐Li Wang, Yan Lu, Mohsen Danaie, Liliana Romero-Resendiz, Stefanus Harjo, Wei Chen, Chenyang Li, Wu Gong, Matthew C. Spink, Ziyang Fan, Jesus Israel S. Palafox
article en

Abstract

Precipitates in structural alloys are conventionally understood as passive obstacles to dislocation motion. Here we show that semi-coherent hexagonal close-packed precipitates in a low-stacking-fault-energy Ni50Co30Ru20 multi-principal element alloy cooperate with planar-fault plasticity in the face-centered cubic matrix. In-situ neutron diffraction, high-resolution electron microscopy, and first-principles calculations reveal that these precipitates interact with and locally modify Shockley-partial-mediated fault structures, are associated with confined, deformation-related interfacial stacking rearrangement, and generate heterogeneous stress fields that sustain work hardening. Phase-resolved diffraction shows that the precipitates yield at an applied stress of ∼1020 MPa and that the load they carry directly is bounded at ∼6–10% of the yield strength, so their contribution mainly acts through the precipitate-matrix interfaces, resulting in a tensile strength of 1038 MPa and 39% uniform elongation. These findings establish a design strategy: coupling low fault energy with deformable phase heterogeneity amplifies planar-fault-mediated strain hardening.Impact statementSemi-coherent precipitates interact with and locally modify planar-fault plasticity, accommodating interfacial rearrangements, and sustaining heterogeneous stress fields, suggesting a design strategy for strong and ductile alloys.

Materials Research Letters
Japan Atomic Energy Agency (JP), City University of Hong Kong (HK), University of Pittsburgh (US), Forschungszentrum Jülich (DE), Ernst Ruska Centre (DE), Japan Proton Accelerator Research Complex (JP), Diamond Light Source (GB), IMDEA Materials (ES), Shenyang Academy of Environmental Sciences (China) (CN), University at Buffalo, State University of New York (US), University of Birmingham (GB), Universidad Nacional Autónoma de México (MX), Bournemouth University (GB)
Diamond Light Source, UK Research and Innovation, European Commission, Ministry of Education, Culture, Sports, Science and Technology, HORIZON EUROPE Framework Programme, Japan Society for the Promotion of Science, Basic and Applied Basic Research Foundation of Guangdong Province
Openalex Percentile: Top 20%
High Entropy Alloys Studies
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