Microstructure and hydrogen content of electrodeposited chromium coating on the inner surface of EP823-SH steel cladding

To reduce corrosion damage to the inner surface of ferritic-martensitic steel fuel rod claddings, additional measures must be taken to increase the corrosion resistance of this steel. One potential approach is applying a chromium coating to the cladding's inner surface. This study investigates the microstructure and hydrogen content of chromium coatings electrodeposited onto the inner surface of fuel rod cladding tubes (internal diameter: 8.7 mm). Under the tested conditions, an electrolyte temperature of 30–35 °C yielded crack-free, equiaxed coatings at a current density ≤ 0.2 A/cm 2 . Higher electrolyte temperatures produce coatings with a columnar structure. Hydrogen accumulation of ∼2 at.% was observed in coatings deposited under optimal conditions. Annealing chromium-coated claddings at 420 °C enables complete hydrogen degassing. Consequently, hydrogen uptake during the chromium plating process will not degrade the cladding's original performance characteristics.

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Publication Details

Journal
Nuclear Engineering and Design
Published
2026-09-11
DOI
https://doi.org/10.1016/j.nucengdes.2026.115211
Primary Topic
Surface Treatment and Coatings
Type
article
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article

Microstructure and hydrogen content of electrodeposited chromium coating on the inner surface of EP823-SH steel cladding

P. S. Dzhumaev, Isayev R. Sh, G.N. Elmanov, I.A. Naumenko et al.
Nuclear Engineering and Design
Surface Treatment and Coatings
article

Microstructure and hydrogen content of electrodeposited chromium coating on the inner surface of EP823-SH steel cladding

P. S. Dzhumaev, Isayev R. Sh, G.N. Elmanov, I.A. Naumenko, A.V. Markin, V.I. Polskij
article en

Abstract

To reduce corrosion damage to the inner surface of ferritic-martensitic steel fuel rod claddings, additional measures must be taken to increase the corrosion resistance of this steel. One potential approach is applying a chromium coating to the cladding's inner surface. This study investigates the microstructure and hydrogen content of chromium coatings electrodeposited onto the inner surface of fuel rod cladding tubes (internal diameter: 8.7 mm). Under the tested conditions, an electrolyte temperature of 30–35 °C yielded crack-free, equiaxed coatings at a current density ≤ 0.2 A/cm 2 . Higher electrolyte temperatures produce coatings with a columnar structure. Hydrogen accumulation of ∼2 at.% was observed in coatings deposited under optimal conditions. Annealing chromium-coated claddings at 420 °C enables complete hydrogen degassing. Consequently, hydrogen uptake during the chromium plating process will not degrade the cladding's original performance characteristics.

Nuclear Engineering and DesignVol. 459
Joint Institute for Nuclear Research (RU), Frumkin Institute of Physical Chemistry and Electrochemistry (RU), National Nuclear Research Center (AZ), "VNIINM" named after AA Bochvar (RU), National Research Nuclear University MEPhI (RU)
Sustainable cities and communities
Openalex Percentile: Top 20%
Surface Treatment and Coatings
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