PORE STRUCTURE AND ELEMENTAL COMPOSITION OF SHARGUN COAL (SURKHANDARYA, UZBEKISTAN): A BASELINE CHARACTERISATION FOR LOCALLY PRODUCED ACTIVATED CARBON

Almost all activated carbon used by industry in Uzbekistan is imported, while the demand for demineralised water — and hence for adsorbent filters — is growing with the country’s hydrogen and thermal power programmes. This work characterises coal from the Shargun deposit (Surkhandarya region) in its pre-activation state, in order to establish a quantitative baseline against which activation regimes can later be judged. Pore structure was determined by nitrogen physisorption at 77.35 K and surface morphology and spot composition by SEM–EDS. The isotherm is convex to the relative-pressure axis over its whole length and shows no point B, which places it close to IUPAC Type III; this is consistent with the BET C constant of 1.799, since within BET theory C < 2 corresponds to Type III and signals that the monolayer assumption does not hold. The multi-point BET area of 8.088 m2 /g is therefore reported for comparison only, and QSDFT is adopted as the primary basis: 12.142 m2 /g, pore volume 0.059 cm3 /g, modal half-width 2.59 nm. No pores narrower than a 2.26 nm half-width were resolved, and about 78 % of the pore volume lies above a 10 nm half-width, so the material is dominated by wide mesopores and interparticle voids rather than by mesopores of the modal size. Carbon accounts for 79.8–82.4 wt.% and sulphur for only 0.16–0.36 wt.%; iron was not detected. Shargun coal cannot serve as an adsorbent as received, but its high carbon content, low sulphur and absence of pyrite make it a promising feedstock for steam activation.

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Publication Details

Journal
Zenodo (CERN European Organization for Nuclear Research)
Published
2026-09-10
DOI
https://doi.org/10.5281/zenodo.22688781
Primary Topic
Minerals Flotation and Separation Techniques
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article
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article

PORE STRUCTURE AND ELEMENTAL COMPOSITION OF SHARGUN COAL (SURKHANDARYA, UZBEKISTAN): A BASELINE CHARACTERISATION FOR LOCALLY PRODUCED ACTIVATED CARBON

S.M. Isayev, A. M. Qudratov
Zenodo (CERN European Organization for Nuclear Research)
Minerals Flotation and Separation Techniques
article

PORE STRUCTURE AND ELEMENTAL COMPOSITION OF SHARGUN COAL (SURKHANDARYA, UZBEKISTAN): A BASELINE CHARACTERISATION FOR LOCALLY PRODUCED ACTIVATED CARBON

S.M. Isayev, A. M. Qudratov
article en

Abstract

Almost all activated carbon used by industry in Uzbekistan is imported, while the demand for demineralised water — and hence for adsorbent filters — is growing with the country’s hydrogen and thermal power programmes. This work characterises coal from the Shargun deposit (Surkhandarya region) in its pre-activation state, in order to establish a quantitative baseline against which activation regimes can later be judged. Pore structure was determined by nitrogen physisorption at 77.35 K and surface morphology and spot composition by SEM–EDS. The isotherm is convex to the relative-pressure axis over its whole length and shows no point B, which places it close to IUPAC Type III; this is consistent with the BET C constant of 1.799, since within BET theory C < 2 corresponds to Type III and signals that the monolayer assumption does not hold. The multi-point BET area of 8.088 m2 /g is therefore reported for comparison only, and QSDFT is adopted as the primary basis: 12.142 m2 /g, pore volume 0.059 cm3 /g, modal half-width 2.59 nm. No pores narrower than a 2.26 nm half-width were resolved, and about 78 % of the pore volume lies above a 10 nm half-width, so the material is dominated by wide mesopores and interparticle voids rather than by mesopores of the modal size. Carbon accounts for 79.8–82.4 wt.% and sulphur for only 0.16–0.36 wt.%; iron was not detected. Shargun coal cannot serve as an adsorbent as received, but its high carbon content, low sulphur and absence of pyrite make it a promising feedstock for steam activation.

Zenodo (CERN European Organization for Nuclear Research)
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Minerals Flotation and Separation Techniques
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PORE STRUCTURE AND ELEMENTAL COMPOSITION OF SHARGUN COAL (SURKHANDARYA, UZBEKISTAN): A BASELINE CHARACTERISATION FOR LOCALLY PRODUCED ACTIVATED CARBON — S.M. Isayev, A. M. Qudratov · Zenodo (CERN European Organization for Nuclear Research) (2026) | TGRS Research Map | TGRS