Research Progress on Acidizing Techniques for Complex-Type Reservoirs

With the continuous decline in easily recoverable reserves of conventional oil and gas, the focus of oil and gas exploration and development has gradually shifted toward complex reservoirs, such as low-permeability, tight, high-temperature and high-pressure (HTHP), and strongly heterogeneous reservoirs. Such reservoirs are characterized by complex pore–throat structures, poor seepage capacity, extreme temperature and pressure conditions, and strong heterogeneity. Traditional acidizing technologies face multiple challenges, including short effective penetration distances, system instability at high temperatures, uneven stimulation, and a tendency to induce secondary formation damage, making it difficult to meet the requirements for highly efficient reservoir stimulation. This paper systematically analyzes the petrophysical properties and acidizing challenges of four typical types of complex reservoirs. It reviews the reaction mechanisms, research and development progress, and reservoir adaptability principles of six acid systems, and elaborates on the application value of molecular simulation technology in acid–rock reaction analysis, formulation optimization, and injection regulation. The review indicates that, under extreme operating conditions, existing technologies still suffer from inadequate system stability, limited deep mass transfer, and environmental concerns. Future research should deepen the understanding of multi-scale acid–rock reaction mechanisms, develop composite acid systems tolerant to extreme conditions, and drive the development of acidizing technologies toward refinement and intelligentization.

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Publication Details

Journal
Molecules
Published
2026-09-10
DOI
https://doi.org/10.3390/molecules31183184
Primary Topic
Hydraulic Fracturing and Reservoir Analysis
Type
article
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article

Research Progress on Acidizing Techniques for Complex-Type Reservoirs

Yujie Bai, Gen Li, Guangsheng Cao, Yifei Sun et al.
Molecules
Hydraulic Fracturing and Reservoir Analysis
article

Research Progress on Acidizing Techniques for Complex-Type Reservoirs

Yujie Bai, Gen Li, Guangsheng Cao, Yifei Sun, Mingxing Bai, Chao Xu, Jingfang Cui, Jiashu Wu
article en

Abstract

With the continuous decline in easily recoverable reserves of conventional oil and gas, the focus of oil and gas exploration and development has gradually shifted toward complex reservoirs, such as low-permeability, tight, high-temperature and high-pressure (HTHP), and strongly heterogeneous reservoirs. Such reservoirs are characterized by complex pore–throat structures, poor seepage capacity, extreme temperature and pressure conditions, and strong heterogeneity. Traditional acidizing technologies face multiple challenges, including short effective penetration distances, system instability at high temperatures, uneven stimulation, and a tendency to induce secondary formation damage, making it difficult to meet the requirements for highly efficient reservoir stimulation. This paper systematically analyzes the petrophysical properties and acidizing challenges of four typical types of complex reservoirs. It reviews the reaction mechanisms, research and development progress, and reservoir adaptability principles of six acid systems, and elaborates on the application value of molecular simulation technology in acid–rock reaction analysis, formulation optimization, and injection regulation. The review indicates that, under extreme operating conditions, existing technologies still suffer from inadequate system stability, limited deep mass transfer, and environmental concerns. Future research should deepen the understanding of multi-scale acid–rock reaction mechanisms, develop composite acid systems tolerant to extreme conditions, and drive the development of acidizing technologies toward refinement and intelligentization.

MoleculesVol. 31(18)
Karamay Central Hospital of Xinjiang (CN), Northeast Petroleum University (CN), Northeastern University (CN), China National Petroleum Corporation (China) (CN)
Openalex Percentile: Top 20%
Hydraulic Fracturing and Reservoir Analysis
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