Metal‐Catalyzed Transformations of Carbon Dioxide Toward the Production of Commodity Chemicals

This perspective examines advances in catalytic methods for converting CO 2 into value‐added commodity chemicals through a future‐facing research and development‐focused viewpoint. As such, select examples that we identify as representative of the field in both mature and underdeveloped technologies are discussed. Transition‐metal catalysis has enabled progress toward the production of acrylic acid derivatives, methylmalonic acids, and cyclic carbonates, despite CO 2 ’s inherent stability. In contrast, other promising transformations, such as the synthesis of amino acids from CO 2 , remain limited by high costs, narrow substrate scope, and poor stereocontrol. Overall, CO 2 utilization offered significant potential as an economic means for sustainable chemical manufacturing while highlighting the need for further catalytic innovation.

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Publication Details

Journal
Advanced Synthesis & Catalysis
Published
2026-08-28
DOI
https://doi.org/10.1002/adsc.70736
Primary Topic
Carbon dioxide utilization in catalysis
Type
article
Field-Weighted Citation Impact
0.00

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article

Metal‐Catalyzed Transformations of Carbon Dioxide Toward the Production of Commodity Chemicals

Craig S. Day, Chaodi Dai, Tu Anh Tran
Advanced Synthesis & Catalysis
Carbon dioxide utilization in catalysis
article

Metal‐Catalyzed Transformations of Carbon Dioxide Toward the Production of Commodity Chemicals

Craig S. Day, Chaodi Dai, Tu Anh Tran
article en

Abstract

This perspective examines advances in catalytic methods for converting CO 2 into value‐added commodity chemicals through a future‐facing research and development‐focused viewpoint. As such, select examples that we identify as representative of the field in both mature and underdeveloped technologies are discussed. Transition‐metal catalysis has enabled progress toward the production of acrylic acid derivatives, methylmalonic acids, and cyclic carbonates, despite CO 2 ’s inherent stability. In contrast, other promising transformations, such as the synthesis of amino acids from CO 2 , remain limited by high costs, narrow substrate scope, and poor stereocontrol. Overall, CO 2 utilization offered significant potential as an economic means for sustainable chemical manufacturing while highlighting the need for further catalytic innovation.

Advanced Synthesis & CatalysisVol. 368(17)
University of Copenhagen (DK)
Novo Nordisk
Industry, innovation and infrastructure
Openalex Percentile: Top 23%
Carbon dioxide utilization in catalysis
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