3D Liquid Crystal Framework Enclosing Dual Compartments

We report a new 3D-ordered liquid-crystal (LC) phase where alkyl and fluoroalkyl side-chains are confined within separate stretched octahedral cages of a tetragonal framework with struts of aromatic rods held together by their hydrogen-bonded ends acting as flexible hinges. This is the first example of a multicolor micellar LC heralding the development of soft and dynamic dual-compartment frameworks, also capable of a martensitic-type phase transition.

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Publication Details

Journal
Angewandte Chemie International Edition
Published
2026-08-26
DOI
https://doi.org/10.1002/anie.7487332
Primary Topic
Liquid Crystal Research Advancements
Type
article
Field-Weighted Citation Impact
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article

3D Liquid Crystal Framework Enclosing Dual Compartments

Feng Liu, Huan-jun LU, Carsten Tschierske, Helgard Ebert et al.
Angewandte Chemie International Edition
Liquid Crystal Research Advancements
article

3D Liquid Crystal Framework Enclosing Dual Compartments

Feng Liu, Huan-jun LU, Carsten Tschierske, Helgard Ebert, Goran Ungar, X. Zeng, Yangyang Zhao, Chunlan Ma
article en

Abstract

We report a new 3D-ordered liquid-crystal (LC) phase where alkyl and fluoroalkyl side-chains are confined within separate stretched octahedral cages of a tetragonal framework with struts of aromatic rods held together by their hydrogen-bonded ends acting as flexible hinges. This is the first example of a multicolor micellar LC heralding the development of soft and dynamic dual-compartment frameworks, also capable of a martensitic-type phase transition.

Angewandte Chemie International Edition
Suzhou University of Science and Technology (CN), Martin Luther University Halle-Wittenberg (DE), Xi'an Jiaotong University (CN), University of Sheffield (GB)
Sustainable cities and communities
Openalex Percentile: Top 26%
Liquid Crystal Research Advancements
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3D Liquid Crystal Framework Enclosing Dual Compartments — Feng Liu, Huan-jun LU, et al. · Angewandte Chemie International Edition (2026) | TGRS Research Map | TGRS