Synthesis and Catalytic Behavior of Ni‐ and Co‐Containing Phyllosilicate Nanoscrolls in Hydrogenation Processes

ABSTRACT In the quest for sustainable and efficient chemical processes, the development of advanced catalytic systems capable of selective hydrogenation under mild conditions stands as a pivotal challenge. This study delves into the use of nanotubular phyllosilicates derived through the thermal reduction of transition metals from a precursor matrix as catalysts for the selective hydrogenation of various unsaturated organic compounds. The investigation explores the catalytic properties of these nanotubular phyllosilicates with relatively lower transition metal loadings, providing insights into their potential for industrial applications. Assumptions about the observed catalytic properties of the obtained samples are proposed based on a number of their structural and morphological features. Notably, the study underscores the significant differences in activity between Ni‐ and Co‐containing samples in different processes.