Is entropy objective? rethinking the foundations of irreversibility and the second law

Abstract The standard formulations of statistical mechanics and the explanations of irreversibility rely on the way we describe physical systems. They use concepts such as coarse-graining or macroscopic states, which depend on the observables used to describe the system and their precision. In this Perspective, we examine the extent to which entropy, irreversibility, and the second law of thermodynamics can be regarded as observer-independent. To this end, we use Einstein's observable-dependent entropy and discuss the objectivity of several concepts and phenomena separately: irreversibility, equilibrium, entropy, temperature, and the second law. We also discuss the role of symmetry-breaking transitions in generating low-entropy states and in the arrow of time, as manifested through traces and footprints. Finally, we discuss the mechanical rationale of the second law based on ergotropy and passive states.

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Publication Details

Journal
PNAS Nexus
Published
2026-08-26
DOI
https://doi.org/10.1093/pnasnexus/pgag288
Primary Topic
Advanced Thermodynamics and Statistical Mechanics
Type
article
Field-Weighted Citation Impact
0.00

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article

Is entropy objective? rethinking the foundations of irreversibility and the second law

Juan M. R. Parrondo
PNAS Nexus
Advanced Thermodynamics and Statistical Mechanics
article

Is entropy objective? rethinking the foundations of irreversibility and the second law

Juan M. R. Parrondo
article en

Abstract

Abstract The standard formulations of statistical mechanics and the explanations of irreversibility rely on the way we describe physical systems. They use concepts such as coarse-graining or macroscopic states, which depend on the observables used to describe the system and their precision. In this Perspective, we examine the extent to which entropy, irreversibility, and the second law of thermodynamics can be regarded as observer-independent. To this end, we use Einstein's observable-dependent entropy and discuss the objectivity of several concepts and phenomena separately: irreversibility, equilibrium, entropy, temperature, and the second law. We also discuss the role of symmetry-breaking transitions in generating low-entropy states and in the arrow of time, as manifested through traces and footprints. Finally, we discuss the mechanical rationale of the second law based on ergotropy and passive states.

PNAS Nexus
Universidad Complutense de Madrid (ES)
Ministerio de Ciencia, Innovación y Universidades, European Regional Development Fund, Agencia Estatal de Investigación
Peace, Justice and strong institutions
Openalex Percentile: Top 10%
Advanced Thermodynamics and Statistical Mechanics
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