Multiple Majorana zero modes realization based on superconducting topological crystalline metal ZrRuAs

The symmetry-protected multiple Majorana zero modes (MZMs) can be manipulated under external fields and have emerged as a promising pathway toward realizing topological quantum computing. While the suitable materials hosting multiple MZMs are still scarce, we propose a feasible candidate platform named superconducting topological crystalline metals (STCMs) that simultaneously possess symmetry-protected topological bands and intrinsic superconductivity. Model analyses demonstrate that the interplay among s-wave superconductivity, mirror symmetry-protected multiple surface Dirac cones, and the introduced spin splitting leads to high BdG Chern numbers of \({\mathcal{N}}=\pm {C}_{M}\) , where C M is the mirror Chern number of the STCM. First-principles calculations identify the experimentally synthesized superconductor ZrRuAs as a promising candidate with C M = 2, hosting two symmetry-protected surface Dirac cones. When integrated into a heterostructure with the ferromagnetic insulator (FMI) such as GdI 2 , a topological superconducting phase with \({\mathcal{N}}=-2\) can be realized, giving rise to two branches of MZMs. This new scheme offers advantages of structural simplicity and tunability, making the FMI/STCM heterostructure an ideal platform for investigating multipole MZMs and novel topological qubits.