Turmeric-Containing Polymer–Mineral Composites with a Waste Cooking Oil-Derived Binder: Physicochemical Characterisation and Exploratory Antimicrobial Screening

Waste cooking oil (WCO) was investigated as a waste-derived reactive precursor for a cured organic binder in highly mineral-filled composites containing turmeric. Ten formulations selected from a broader experimental screening were prepared from WCO, sulfuric acid, quartz sand, and turmeric added at 1–7% relative to the dry mass of quartz sand. Formulation-specific thermal curing was conducted at 190–210 °C for 12–20 h. Because the binder content, acid-to-binder ratio, turmeric content, curing temperature, and curing time varied simultaneously, the study was designed as an exploratory multifactorial screening rather than as a controlled assessment of individual processing variables. FTIR, 1H NMR analysis of acetone-soluble constituents, TGA, and SEM-EDS were combined with mechanical screening, water-absorption, contact-angle, and microbiological measurements. Bending and splitting tensile strengths ranged from 1.15 to 2.42 MPa and from 0.30 to 0.52 MPa, respectively. Water absorption ranged from approximately 4.8% to 9.0%, while water contact angles exceeded 90° for all investigated formulations. Selected formulations reduced the surviving fraction by more than 90% for Staphylococcus epidermidis and by approximately 70% for Pseudomonas aeruginosa under the applied suspension-assay conditions. The estimated C50 values of 60.6–83.3 mg mL−1 indicated measurable concentration-dependent responses at relatively high nominal composite concentrations. The available results support curing-associated transformation and consolidation of the WCO-derived binder phase but do not quantify crosslink density or retained organic content. Because no matched turmeric-free composite or surface/eluate pH measurements were available, the biological effects are attributed to the complete composite formulations rather than specifically to turmeric or intact curcumin. The results provide an exploratory basis for the further development of waste-derived, non-load-bearing polymer–mineral composites with functional surface and biological properties.

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Journal
Materials
Published
2026-08-24
DOI
https://doi.org/10.3390/ma19173583
Primary Topic
Polymer composites and self-healing
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article
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article

Turmeric-Containing Polymer–Mineral Composites with a Waste Cooking Oil-Derived Binder: Physicochemical Characterisation and Exploratory Antimicrobial Screening

Zbigniew Rozwadowski, Barbara Pucelik, Magda Kijania-Kontak, Mateusz Barczewski et al.
Materials
Polymer composites and self-healing
article

Turmeric-Containing Polymer–Mineral Composites with a Waste Cooking Oil-Derived Binder: Physicochemical Characterisation and Exploratory Antimicrobial Screening

Zbigniew Rozwadowski, Barbara Pucelik, Magda Kijania-Kontak, Mateusz Barczewski, Sandra Paszkiewicz, Paweł Staroń, Anita Staroń, Agata Barzowska-Gogola
article en

Abstract

Waste cooking oil (WCO) was investigated as a waste-derived reactive precursor for a cured organic binder in highly mineral-filled composites containing turmeric. Ten formulations selected from a broader experimental screening were prepared from WCO, sulfuric acid, quartz sand, and turmeric added at 1–7% relative to the dry mass of quartz sand. Formulation-specific thermal curing was conducted at 190–210 °C for 12–20 h. Because the binder content, acid-to-binder ratio, turmeric content, curing temperature, and curing time varied simultaneously, the study was designed as an exploratory multifactorial screening rather than as a controlled assessment of individual processing variables. FTIR, 1H NMR analysis of acetone-soluble constituents, TGA, and SEM-EDS were combined with mechanical screening, water-absorption, contact-angle, and microbiological measurements. Bending and splitting tensile strengths ranged from 1.15 to 2.42 MPa and from 0.30 to 0.52 MPa, respectively. Water absorption ranged from approximately 4.8% to 9.0%, while water contact angles exceeded 90° for all investigated formulations. Selected formulations reduced the surviving fraction by more than 90% for Staphylococcus epidermidis and by approximately 70% for Pseudomonas aeruginosa under the applied suspension-assay conditions. The estimated C50 values of 60.6–83.3 mg mL−1 indicated measurable concentration-dependent responses at relatively high nominal composite concentrations. The available results support curing-associated transformation and consolidation of the WCO-derived binder phase but do not quantify crosslink density or retained organic content. Because no matched turmeric-free composite or surface/eluate pH measurements were available, the biological effects are attributed to the complete composite formulations rather than specifically to turmeric or intact curcumin. The results provide an exploratory basis for the further development of waste-derived, non-load-bearing polymer–mineral composites with functional surface and biological properties.

MaterialsVol. 19(17)
West Pomeranian University of Technology in Szczecin (PL), Cracow University of Technology (PL), Cracow University of Technology (PL), Poznań University of Technology (PL)
Narodowe Centrum Badań i Rozwoju
Openalex Percentile: Top 21%
Polymer composites and self-healing
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