Plasmonic Field-Enhanced Raman Sensing Enables Rapid Trace Methanol Detection in Transformer Oil

Methanol is a critical molecular marker for the early aging of oil-paper insulation, and its rapid detection is highly valuable for insulation condition assessment and the fault warning of power transformers. Widely used chromatographic methods require sophisticated pretreatment workflow and are not suitable for in situ monitoring. Non-destructive spectroscopic methods remain challenging due to the intrinsically small cross section of trace molecules in complex liquid environments. The rapid, direct detection of trace methanol in an oil mixture has yet to be demonstrated. In this study, a high-performance Raman-enhancing substrate was developed through hierarchical microstructure regulation, combining microscale light-trapping structures and nanoscale field-confinement sites to sense the weak Raman response of methanol in transformer oil. Direct detection of ppm-level methanol in the oil matrix was achieved, without additional adsorption enrichment or other complicated pretreatment procedures. The characteristic Raman band of methanol in transformer oil was identified, and a quantitative sensing method was established. Furthermore, the intrinsic temperature-dependent Raman response of methanol was investigated to evaluate the stability of its characteristic fingerprint bands over a broad temperature range. This work demonstrates a rapid, sensitive, and pretreatment-free spectroscopic strategy for trace methanol detection in complex oil matrices, and also sheds light on the high-sensitivity detection of small molecular markers in complex liquid environments.