Atomic Layer Deposition of AlO <sub> <i>x</i> </sub> /SnO <sub> <i>y</i> </sub> Passivating Charge Transport Bilayer for Silicon Solar Cells

Post‐deposition treatment of AlO x /SnO y bilayer obtained by atomic layer deposition on FZ n‐type Si enhances the effective carrier lifetime beyond values realized with either material individually. The improved passivation is attributed to the 15 nm thick capping SnO y layer, which effectively suppresses outward hydrogen effusion. Replacing the conventional emitter passivation layer in a Passivated Emitter Rear Contact (PERC) cell with this bilayer stack results in an absolute efficiency gain of 2.4% under rear illumination. Device simulations identify the probable mechanisms as improved rear surface passivation and rear‐side doping, both induced by the processing conditions of the bilayer. The PC1D simulations predict that processing‐induced rear side improvements coupled with the enhanced front side passivation should enable PERC‐based cells with bifacial power conversion efficiency exceeding 25%.

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Publication Details

Journal
Solar RRL
Published
2026-08-17
DOI
https://doi.org/10.1002/solr.70452
Primary Topic
Silicon and Solar Cell Technologies
Type
article
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Atomic Layer Deposition of AlO x /SnO y Passivating Charge Transport Bilayer for Silicon Solar Cells

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Atomic Layer Deposition of AlO x /SnO y Passivating Charge Transport Bilayer for Silicon Solar Cells

Sushobhita Chawla, Kanhaiya Lal, Kavaipatti Ramanathan Balasubramaniam, Pradeep R. Nair, Abhijit Kumar Singha, Karthik Raitani, Garima Aggarwal, Prahlad Prajapat, Bireswar Mandol
article en

Abstract

Post‐deposition treatment of AlO x /SnO y bilayer obtained by atomic layer deposition on FZ n‐type Si enhances the effective carrier lifetime beyond values realized with either material individually. The improved passivation is attributed to the 15 nm thick capping SnO y layer, which effectively suppresses outward hydrogen effusion. Replacing the conventional emitter passivation layer in a Passivated Emitter Rear Contact (PERC) cell with this bilayer stack results in an absolute efficiency gain of 2.4% under rear illumination. Device simulations identify the probable mechanisms as improved rear surface passivation and rear‐side doping, both induced by the processing conditions of the bilayer. The PC1D simulations predict that processing‐induced rear side improvements coupled with the enhanced front side passivation should enable PERC‐based cells with bifacial power conversion efficiency exceeding 25%.

Solar RRLVol. 10(15)
Indian Institute of Technology Bombay (IN), Institut of Research in Solar Energy and New Energies (MA)
Affordable and clean energy
Openalex Percentile: Top 18%
Silicon and Solar Cell Technologies
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