Beyond the working curve: industrial perspectives on cross-platform process equivalence in vat photopolymerization

Context. The working curve introduced by Jacobs remains a widely used reference for characterising cure depth as a function of radiant exposure in vat photopolymerization. Recent interlaboratory studies have shown that conventionally measured working-curve parameters can vary markedly between laboratories and that improved spectral control and procedural standardisation substantially improve reproducibility. Position. Working-curve agreement is necessary for meaningful comparison, but it is not sufficient to establish cross-platform process equivalence. Part-level outcomes can also depend on the spectral distribution and spatial delivery of light, oxygen-related interfacial effects and thermal conditions, and the state and handling history of the resin. Approach. This Perspective surveys peer-reviewed literature and public standards relevant to working-curve measurement, optical delivery, oxygen inhibition, process-parameter sensitivity and additive-manufacturing qualification. Three observation domains are used to organise the discussion: spectral, atmospheric and material-history. They are presented as categories for observation rather than as a causal model or ranked hierarchy. Implications. Cross-platform qualification should therefore retain the working curve as a metrological anchor while confirming performance at part level under the operational conditions of intended use. Scope. No new experimental data, universal equivalence criterion or quantitative causal hierarchy is proposed.

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Publication Details

Journal
Zenodo (CERN European Organization for Nuclear Research)
Published
2026-08-18
DOI
https://doi.org/10.5281/zenodo.21996903
Primary Topic
Photopolymerization techniques and applications
Type
preprint
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preprint

Beyond the working curve: industrial perspectives on cross-platform process equivalence in vat photopolymerization

Juan Segurola
Zenodo (CERN European Organization for Nuclear Research)
Photopolymerization techniques and applications
preprint

Beyond the working curve: industrial perspectives on cross-platform process equivalence in vat photopolymerization

Juan Segurola
preprint en

Abstract

Context. The working curve introduced by Jacobs remains a widely used reference for characterising cure depth as a function of radiant exposure in vat photopolymerization. Recent interlaboratory studies have shown that conventionally measured working-curve parameters can vary markedly between laboratories and that improved spectral control and procedural standardisation substantially improve reproducibility. Position. Working-curve agreement is necessary for meaningful comparison, but it is not sufficient to establish cross-platform process equivalence. Part-level outcomes can also depend on the spectral distribution and spatial delivery of light, oxygen-related interfacial effects and thermal conditions, and the state and handling history of the resin. Approach. This Perspective surveys peer-reviewed literature and public standards relevant to working-curve measurement, optical delivery, oxygen inhibition, process-parameter sensitivity and additive-manufacturing qualification. Three observation domains are used to organise the discussion: spectral, atmospheric and material-history. They are presented as categories for observation rather than as a causal model or ranked hierarchy. Implications. Cross-platform qualification should therefore retain the working curve as a metrological anchor while confirming performance at part level under the operational conditions of intended use. Scope. No new experimental data, universal equivalence criterion or quantitative causal hierarchy is proposed.

Zenodo (CERN European Organization for Nuclear Research)
Dynavax Technologies (Germany) (DE)
Photopolymerization techniques and applications
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