SCAPS-1D Simulation of Lead-Free CH3NH3SnBr3 Perovskite Solar Cells: Impact of Temperature on Photovoltaic and Impedance Performance

The rise in the need for sustainable energy has facilitated the advancement of perovskite solar cells (PSCs) as potential substitutes for traditional photovoltaic technologies. Nevertheless, their performance is very sensitive to environmental factors, especially temperature, which influences the charge transport and recombination processes. This paper examines the thermal effect on the electrical characteristics and impedance response of lead-free PSCs in accordance with the FTO/ETL (C60, PCBM, SnS2, ZnSe)/CH3NH3SnBr3/Cu2O configuration. The experiments were performed with SCAPS-1D under usual illumination, using a combination of current-voltage analysis and impedance spectroscopy between 270 and 400 K. The findings indicate that there is a significant reduction in open-circuit voltage with higher temperature, whereas the short-circuit current density does not change much. The enhancement of the fill factor increases and then decreases with increased temperature, leading to a net decrease in power conversion efficiency because of the increased recombination. The impedance analysis is also an indicator of lower recombination resistance and accelerated charge carrier dynamics. These results demonstrate that thermal control and interface optimization can be important for enhancing PSC performance.