Photoredox Catalytic Sulfonylation/Cyclization of Allyl‐Tethered Aroyl Ketene Dithioacetals Toward Sulfonated Benzoxepines

A general and efficient methodology for the synthesis of benzoxepine derivatives via visible‐light‐induced regioselective radical cyclization has been developed. This method has good regioselectivity, is operationally simple, and exhibits high‐functional group tolerance.

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Publication Details

Journal
European Journal of Organic Chemistry
Published
2026-08-13
DOI
https://doi.org/10.1002/ejoc.70746
Primary Topic
Sulfur-Based Synthesis Techniques
Type
article
Field-Weighted Citation Impact
0.00

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article

Photoredox Catalytic Sulfonylation/Cyclization of Allyl‐Tethered Aroyl Ketene Dithioacetals Toward Sulfonated Benzoxepines

Nengneng Zhou, Anxu Pan, Cuifu Jiang, Bin Sheng et al.
European Journal of Organic Chemistry
Sulfur-Based Synthesis Techniques
article

Photoredox Catalytic Sulfonylation/Cyclization of Allyl‐Tethered Aroyl Ketene Dithioacetals Toward Sulfonated Benzoxepines

Nengneng Zhou, Anxu Pan, Cuifu Jiang, Bin Sheng, Man Zhang, Wanqing Zhao
article en

Abstract

A general and efficient methodology for the synthesis of benzoxepine derivatives via visible‐light‐induced regioselective radical cyclization has been developed. This method has good regioselectivity, is operationally simple, and exhibits high‐functional group tolerance.

European Journal of Organic Chemistry
Anhui Normal University (CN)
National Natural Science Foundation of China
Openalex Percentile: Top 18%
Sulfur-Based Synthesis Techniques
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