Activity enhances transport while competing interactions preserve structure in colloidal microphase formers

Colloidal models with short-range attraction and long range repulsion (SALR) have been extensively studied using theoretical and simulations methods due to their rich and universal equilibrium phase behavior. Using Brownian dynamics simulations, we study the dynamical phase behavior of active suspensions in which colloidal particles interact with each other via a SALR potential. Upon increasing the self-propulsion force of the particles, we observed that the structural transitions the active suspension undergoes resemble those observed in its passive counterpart by increasing the temperature of the thermal bath. However, when looking at the transport properties of active and passive suspensions with similar structure, we observed a clear mismatch. We demonstrated that increasing the activity enhances the particles mobility within the SALR fluid while simultaneously preserving the structure. This leads to a structure-dynamics decoupling induced by the activity while highlighting the structural memory of SALR potentials under non-equilibrium conditions.

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Publication Details

Journal
The Journal of Chemical Physics
Published
2026-08-03
DOI
https://doi.org/10.1063/5.0343447
Primary Topic
Micro and Nano Robotics
Type
article
Field-Weighted Citation Impact
0.00

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article

Activity enhances transport while competing interactions preserve structure in colloidal microphase formers

Horacio Serna, José Martín‐Roca, Eva G. Noya, Ariel G. Meyra
The Journal of Chemical Physics
Micro and Nano Robotics
article

Activity enhances transport while competing interactions preserve structure in colloidal microphase formers

Horacio Serna, José Martín‐Roca, Eva G. Noya, Ariel G. Meyra
article en

Abstract

Colloidal models with short-range attraction and long range repulsion (SALR) have been extensively studied using theoretical and simulations methods due to their rich and universal equilibrium phase behavior. Using Brownian dynamics simulations, we study the dynamical phase behavior of active suspensions in which colloidal particles interact with each other via a SALR potential. Upon increasing the self-propulsion force of the particles, we observed that the structural transitions the active suspension undergoes resemble those observed in its passive counterpart by increasing the temperature of the thermal bath. However, when looking at the transport properties of active and passive suspensions with similar structure, we observed a clear mismatch. We demonstrated that increasing the activity enhances the particles mobility within the SALR fluid while simultaneously preserving the structure. This leads to a structure-dynamics decoupling induced by the activity while highlighting the structural memory of SALR potentials under non-equilibrium conditions.

The Journal of Chemical PhysicsVol. 165(5)
Consejo Superior de Investigaciones Científicas (ES), Instituto de Física Fundamental (ES), Instituto de Fisica de Liquidos y Sistemas Biologicos (AR), Instituto de Química Física Blas Cabrera (ES), Universitat de Barcelona (ES)
Ministerio de Ciencia e Innovación, Agencia Estatal de Investigación, HORIZON EUROPE Marie Sklodowska-Curie Actions
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Micro and Nano Robotics
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Activity enhances transport while competing interactions preserve structure in colloidal microphase formers — Horacio Serna, José Martín‐Roca, et al. · The Journal of Chemical Physics (2026) | TGRS Research Map | TGRS