Dynamic and Post-Deformation Static Aging as an Integrated Approach to Thermomechanical Processing of TiNi Shape Memory Alloys

The effect of thermomechanical processing (TMP) parameters on the structural-phase evolution and properties of Ni-enriched Ti–50.8 at.% Ni shape memory alloy was investigated. Compression deformation was performed at T = 300–500 °C, accompanied by the development of dynamic aging (DA) processes, to true strains of e = 0.5–1.3, followed by post-deformation static aging (SA) at 430 °C for 1 and 10 h. The structural-phase state and properties were characterized using optical and transmission electron microscopy, X-ray diffraction, differential scanning calorimetry, and Vickers hardness measurements. The results confirmed that DA processes were activated during compression but proved insufficient for pronounced Ti3Ni4 precipitate growth compared with SA. The temperature range of 430–500 °C promoted the most intensive DA processes and facilitated ultrafine-grained structure formation. The processing route combining DA at 500 °C with short-term SA (1 h) resulted in the finest precipitates of Ti3Ni4 phase and most homogeneous substructure. These findings demonstrate that the proposed TMP strategy enables effective tailoring of precipitate dispersion, evolution of transformation temperatures and mechanical properties (hardness), providing a viable manufacturing pathway for tailoring TiNi SMA performance in advanced biomedical and engineering applications.