Chemical Transformations of Adamantan-2-ylidenemalonic Acid and Its Derivatives
Abstract The acylation behavior of several nucleophiles with adamantan-2-ylidenemalonic acid dichloride was investigated. The reactivity of adamantan-2-ylidenemalonic acid and its derivatives toward reducing systems was examined. A skeletal rearrangement of adamantan-2-ylidenemalonic acid in liquid bromine was revealed, affording bromolactones possessing a protoadamantane framework.
Authors
- Anastasiya N. Bogdanova (ORCID: https://orcid.org/0000-0003-2805-6180)
- Yu. N. Klimochkin (ORCID: https://orcid.org/0000-0002-7335-4040)
- Andrei V. Merzlyakov (ORCID: https://orcid.org/0009-0004-9612-8267)
Institutions
- Samara State Technical University (RU)
Publication Details
- Journal
- Russian Journal of General Chemistry
- Published
- 2026-07-30
- DOI
- https://doi.org/10.1134/s1070363225608440
- Primary Topic
- Eicosanoids and Hypertension Pharmacology
- Type
- article
- Field-Weighted Citation Impact
- 0.00