Pd <sub>24</sub> Cu <sub>12</sub> Cages with Open Tripalladium Nodes for Selective Hydrogenation
units. Such a rigid framework, together with the electronic communication among the metal centers, accounts for the exceptional thermal and aerobic stability of the cage. Notably, the cage showcases high catalytic activity and selectivity in the hydrogenation of azobenzene. These findings not only introduce a class of catalytically active palladium nodes for the assembly of chemically different palladium-organic cages but also pave the way for further exploration of cage-based catalysts in hydrogenation processes.
Authors
- Jianyu Wei (ORCID: https://orcid.org/0000-0001-8540-2233)
- Dongjie Zuo (ORCID: https://orcid.org/0009-0007-1738-1312)
- Nanfeng Zheng (ORCID: https://orcid.org/0000-0001-9879-4790)
- Zi‐Ang Nan (ORCID: https://orcid.org/0000-0003-0635-9789)
- J Sun
- Hui Cun Shen (ORCID: https://orcid.org/0000-0003-4800-437X)
- Qingyuan Wu (ORCID: https://orcid.org/0000-0002-9016-0846)
- Yi-Xiang Wang (ORCID: https://orcid.org/0000-0002-5246-5497)
- Fugui He
- Bo Gao
- Bingzheng Yan
- Qinghua Xu (ORCID: https://orcid.org/0009-0009-8638-4474)
- Rong Huo
- Huifang Guo
Institutions
- Xiamen University (CN)
- Chinese Academy of Sciences (CN)
- Ningxia University (CN)
- Inner Mongolia University (CN)
- Xiamen Institute of Rare-earth Materials (CN)
- Fujian Institute of Research on the Structure of Matter (CN)
- Advanced Energy Materials (United States) (US)
- Tan Kah Kee Innovation Laboratory (CN)
- Collaborative Innovation Center of Chemistry for Energy Materials (CN)
Publication Details
- Journal
- Journal of the American Chemical Society
- Published
- 2026-07-26
- DOI
- https://doi.org/10.1021/jacs.6c05465
- Primary Topic
- Supramolecular Chemistry and Complexes
- Type
- article
- Field-Weighted Citation Impact
- 0.00