Spin Manipulation Effect in Photodeprotection Reaction Using Triplet Ground-State Cation
were investigated by ultrafast transient absorption spectroscopy, while its reactivity was elucidated through chemical trapping experiments by benzyl bromide, molecular oxygen, and ferrocene. This study demonstrates spin manipulation as a new strategy for boosting the efficiency of photodeprotection reactions. Notably, a remarkably high deprotection selectivity of 92% was achieved.
Authors
- Y Takara
- Ryohei Kishi (ORCID: https://orcid.org/0000-0002-6005-7629)
- Yukihide Ishibashi (ORCID: https://orcid.org/0000-0002-4015-8828)
- Manabu Abe (ORCID: https://orcid.org/0000-0002-2013-4394)
- Ma‐aya Takano
Institutions
- Hiroshima University (JP)
- Toneyama National Hospital (JP)
- Ehime University (JP)
- The University of Osaka (JP)
Publication Details
- Journal
- Journal of the American Chemical Society
- Published
- 2026-07-26
- DOI
- https://doi.org/10.1021/jacs.6c10051
- Primary Topic
- Advanced oxidation water treatment
- Type
- article
- Field-Weighted Citation Impact
- 0.00